New organic-inorganic hybrid materials based on DTDH-TTP and paramagnetic isothiocyanato complex anion: (DTDH-TTP)2[Cr(phen)(NCS)4]· CH2Cl2

F. Setifi; L. Ouahab; A. Miyazaki; T. Enoki; J. Yamada

doi:10.1016/S0379-6779(02)01052-7

New organic-inorganic hybrid materials based on DTDH-TTP and paramagnetic isothiocyanato complex anion: (DTDH-TTP)₂[Cr(phen)(NCS)₄]· CH₂Cl₂

F. Setifi, L. Ouahab^*, A. Miyazaki, T. Enoki, J. Yamada

^*この論文の責任著者

工学科　応用化学コース

研究成果: ジャーナルへの寄稿 › 会議記事 › 査読

4 被引用数 (Scopus)

抄録

The preparation, X-ray crystal structures and magnetic properties of (DTDH-TTP)₂[Cr(phen)(NCS)₄].CH₂Cl₂ are reported. Crystal data triclinic, space group P1̄, a = 7.9167(1), b = 11.1292(2), c = 29.4844(7)Å, α = 83.335(1), β = 87.701(1), γ = 82.676(1)°, V = 2558.32(8)Å³, Z = 2, R = 0.0591 based on 4938 reflections with I > 2σ(I). This salt shows semiconductive behavior (σ_RT = 0.1 S cm^-1, E_A = 1400 K), which can be understood as a consequence of the tetramerized structure of the donor alignment. The magnetic susceptibility obeys the Curie-Weiss law with the Curie constant C = 1.90 emu K mo1^-1 and the Weiss temperature Θ = -0.8 K.

本文言語	英語
ページ（範囲）	1177-1179
ページ数	3
ジャーナル	Synthetic Metals
巻	137
号	1-3
DOI	https://doi.org/10.1016/S0379-6779(02)01052-7
出版ステータス	出版済み - 2003/04/04
イベント	ICSM 2002 - Shanghai, 中国継続期間: 2002/06/29 → 2002/07/05

ASJC Scopus 主題領域

電子材料、光学材料、および磁性材料
凝縮系物理学
材料力学
機械工学
金属および合金
材料化学

文献へのアクセス

10.1016/S0379-6779(02)01052-7

フィンガープリント

「New organic-inorganic hybrid materials based on DTDH-TTP and paramagnetic isothiocyanato complex anion: (DTDH-TTP)₂[Cr(phen)(NCS)₄]· CH₂Cl₂」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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title = "New organic-inorganic hybrid materials based on DTDH-TTP and paramagnetic isothiocyanato complex anion: (DTDH-TTP)2[Cr(phen)(NCS)4]· CH2Cl2",

abstract = "The preparation, X-ray crystal structures and magnetic properties of (DTDH-TTP)2[Cr(phen)(NCS)4].CH2Cl2 are reported. Crystal data triclinic, space group P{\=1}, a = 7.9167(1), b = 11.1292(2), c = 29.4844(7){\AA}, α = 83.335(1), β = 87.701(1), γ = 82.676(1)°, V = 2558.32(8){\AA}3, Z = 2, R = 0.0591 based on 4938 reflections with I > 2σ(I). This salt shows semiconductive behavior (σRT = 0.1 S cm-1, EA = 1400 K), which can be understood as a consequence of the tetramerized structure of the donor alignment. The magnetic susceptibility obeys the Curie-Weiss law with the Curie constant C = 1.90 emu K mo1-1 and the Weiss temperature Θ = -0.8 K.",

keywords = "Chromium, Conductivity, Crystal structure, DTDH-TTP, Isothiocyanato complex, Magnetism",

author = "F. Setifi and L. Ouahab and A. Miyazaki and T. Enoki and J. Yamada",

year = "2003",

month = apr,

day = "4",

doi = "10.1016/S0379-6779(02)01052-7",

language = "英語",

volume = "137",

pages = "1177--1179",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

number = "1-3",

note = "ICSM 2002 ; Conference date: 29-06-2002 Through 05-07-2002",

}

TY - JOUR

T1 - New organic-inorganic hybrid materials based on DTDH-TTP and paramagnetic isothiocyanato complex anion

T2 - ICSM 2002

AU - Setifi, F.

AU - Ouahab, L.

AU - Miyazaki, A.

AU - Enoki, T.

AU - Yamada, J.

PY - 2003/4/4

Y1 - 2003/4/4

N2 - The preparation, X-ray crystal structures and magnetic properties of (DTDH-TTP)2[Cr(phen)(NCS)4].CH2Cl2 are reported. Crystal data triclinic, space group P1̄, a = 7.9167(1), b = 11.1292(2), c = 29.4844(7)Å, α = 83.335(1), β = 87.701(1), γ = 82.676(1)°, V = 2558.32(8)Å3, Z = 2, R = 0.0591 based on 4938 reflections with I > 2σ(I). This salt shows semiconductive behavior (σRT = 0.1 S cm-1, EA = 1400 K), which can be understood as a consequence of the tetramerized structure of the donor alignment. The magnetic susceptibility obeys the Curie-Weiss law with the Curie constant C = 1.90 emu K mo1-1 and the Weiss temperature Θ = -0.8 K.

AB - The preparation, X-ray crystal structures and magnetic properties of (DTDH-TTP)2[Cr(phen)(NCS)4].CH2Cl2 are reported. Crystal data triclinic, space group P1̄, a = 7.9167(1), b = 11.1292(2), c = 29.4844(7)Å, α = 83.335(1), β = 87.701(1), γ = 82.676(1)°, V = 2558.32(8)Å3, Z = 2, R = 0.0591 based on 4938 reflections with I > 2σ(I). This salt shows semiconductive behavior (σRT = 0.1 S cm-1, EA = 1400 K), which can be understood as a consequence of the tetramerized structure of the donor alignment. The magnetic susceptibility obeys the Curie-Weiss law with the Curie constant C = 1.90 emu K mo1-1 and the Weiss temperature Θ = -0.8 K.

KW - Chromium

KW - Conductivity

KW - Crystal structure

KW - DTDH-TTP

KW - Isothiocyanato complex

KW - Magnetism

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U2 - 10.1016/S0379-6779(02)01052-7

DO - 10.1016/S0379-6779(02)01052-7

M3 - 会議記事

AN - SCOPUS:0037419448

SN - 0379-6779

VL - 137

SP - 1177

EP - 1179

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

Y2 - 29 June 2002 through 5 July 2002

ER -