Magnetic nanoparticle-supported iodoarene oxidative catalysts and its application to phenol oxidation

Hisanori Nambu; Ikumi Shimokawa; Tomoya Fujiwara; Takayuki Yakura

doi:10.1007/978-981-10-3421-3_9

Magnetic nanoparticle-supported iodoarene oxidative catalysts and its application to phenol oxidation

Hisanori Nambu, Ikumi Shimokawa, Tomoya Fujiwara, Takayuki Yakura^*

^*この論文の責任著者

分子合成化学研究室

研究成果: 書籍の章/レポート/会議録 › 章 › 査読

2 被引用数 (Scopus)

抄録

Iodoarene oxidative catalysts immobilized on magnetite (Fe3O4) were developed. The catalysts showed reactivities similar to that of 4-iodophenoxyacetic acid for the oxidation of 4-alkoxyphenols in the presence of Oxone® as a co-oxidant. In addition, they were easily recovered by the use of an external magnet and could be recycled up to eight times. The oxidation of various 4-alkoxyphenols with the catalyst proceeded smoothly at room temperature to give the corresponding p-quinones in good to high yields. This is the first example of a magnetic nanoparticle-supported iodoarene catalyst.

本文言語	英語
ホスト出版物のタイトル	New Horizons of Process Chemistry
ホスト出版物のサブタイトル	Scalable Reactions and Technologies
出版社	Springer Singapore
ページ	121-129
ページ数	9
ISBN（電子版）	9789811034213
ISBN（印刷版）	9789811034206
DOI	https://doi.org/10.1007/978-981-10-3421-3_9
出版ステータス	出版済み - 2017/01/01

ASJC Scopus 主題領域

化学一般
化学工学一般
医学一般
工学一般
農業および生物科学一般

文献へのアクセス

10.1007/978-981-10-3421-3_9

引用スタイル

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abstract = "Iodoarene oxidative catalysts immobilized on magnetite (Fe3O4) were developed. The catalysts showed reactivities similar to that of 4-iodophenoxyacetic acid for the oxidation of 4-alkoxyphenols in the presence of Oxone{\textregistered} as a co-oxidant. In addition, they were easily recovered by the use of an external magnet and could be recycled up to eight times. The oxidation of various 4-alkoxyphenols with the catalyst proceeded smoothly at room temperature to give the corresponding p-quinones in good to high yields. This is the first example of a magnetic nanoparticle-supported iodoarene catalyst.",

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AU - Nambu, Hisanori

AU - Shimokawa, Ikumi

AU - Fujiwara, Tomoya

AU - Yakura, Takayuki

N1 - Publisher Copyright: © Springer Nature Singapore Pte Ltd. 2017.

PY - 2017/1/1

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N2 - Iodoarene oxidative catalysts immobilized on magnetite (Fe3O4) were developed. The catalysts showed reactivities similar to that of 4-iodophenoxyacetic acid for the oxidation of 4-alkoxyphenols in the presence of Oxone® as a co-oxidant. In addition, they were easily recovered by the use of an external magnet and could be recycled up to eight times. The oxidation of various 4-alkoxyphenols with the catalyst proceeded smoothly at room temperature to give the corresponding p-quinones in good to high yields. This is the first example of a magnetic nanoparticle-supported iodoarene catalyst.

AB - Iodoarene oxidative catalysts immobilized on magnetite (Fe3O4) were developed. The catalysts showed reactivities similar to that of 4-iodophenoxyacetic acid for the oxidation of 4-alkoxyphenols in the presence of Oxone® as a co-oxidant. In addition, they were easily recovered by the use of an external magnet and could be recycled up to eight times. The oxidation of various 4-alkoxyphenols with the catalyst proceeded smoothly at room temperature to give the corresponding p-quinones in good to high yields. This is the first example of a magnetic nanoparticle-supported iodoarene catalyst.

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Magnetic nanoparticle-supported iodoarene oxidative catalysts and its application to phenol oxidation

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