Intense Fluorescence of Metal-to-Ligand Charge Transfer in [Pt(0)(binap)₂] [binap = 2,2′-Bis(diphenylphosphino)-1,1′ -binaphthyl]

Keyphrases

• Ligand-to-metal Charge Transfer 100%
• 1,1′-binaphthyl 100%
• BINAP 100%
• Luminescence 75%
• Spin-orbit Coupling 75%
• Prompt Fluorescence 75%
• Quantum Yield 50%
• Phosphorescence 50%
• Energy Difference 50%
• Large Energy 50%
• Low Temperature 25%
• Picosecond 25%
• Sub-picosecond 25%
• Molecular Orbital 25%
• Ambient Temperature 25%
• Density Functional Theory 25%
• Steady State 25%
• Radiative Rates 25%
• Transient Absorption Spectra 25%
• Toluene 25%
• Structural Distortion 25%
• Time-correlated Single-photon Counting (TCSPC) 25%
• Energy Splitting 25%
• Thermally Activated Processes 25%
• Spin-orbit Coupling Constants 25%
• Delayed Fluorescence 25%
• Intensity Borrowing 25%
• Temperature-dependent Emission 25%
• Stimulated Emission 25%

Chemistry

• Charge Transfer State 100%
• Quantum Yield 100%
• Molecular Orbital 50%
• Density Functional Theory 50%
• Spin-Orbit Coupling 50%
• Delayed Fluorescence 50%
• Stimulated Emission 50%
• Absorption Spectra 50%