@article{e28a8c52b22344cfaf23ed9328ce7ad6,
title = "First enantioselective synthesis of a hydroxyindolizidine alkaloid from the ant Myrmicaria melanogaster",
abstract = "The first enantioselective synthesis of the recently reported ant alkaloid 1 has been achieved starting from commercially available lactam 3 in seven steps and 25% overall yield. The proposed structure of the natural product was confirmed by comparison with synthetic 1 and its absolute configuration established as 3S,5R,8S,9S.",
keywords = "Chelation control, Hydroxyindolizidine, Myrmicaria melanogaster, New ant alkaloid, Venoms of ant",
author = "Naoki Toyooka and Dejun Zhou and Hideo Nemoto and Yasuhiro Tezuka and Shigetoshi Kadota and Jones, {Tappey H.} and Garraffo, {H. Martin} and Spande, {Thomas F.} and Daly, {John W.}",
year = "2008",
month = jul,
day = "16",
doi = "10.1055/s-2008-1078502",
language = "英語",
pages = "1894--1896",
journal = "Synlett",
issn = "0936-5214",
publisher = "Georg Thieme Verlag",
number = "12",
}