Facile and efficient sulfenylation method using quinone mono-O,S-acetals under mild conditions

M. Matsugi; K. Murata; K. Gotanda; H. Nambu; G. Anilkumar; K. Matsumoto; Y. Kita

doi:10.1021/jo001710q

Facile and efficient sulfenylation method using quinone mono-O,S-acetals under mild conditions

M. Matsugi, K. Murata, K. Gotanda, H. Nambu, G. Anilkumar, K. Matsumoto, Y. Kita^*

^*この論文の責任著者

分子合成化学研究室

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

131 被引用数 (Scopus)

抄録

A novel sulfenylation method induced by aromatization of quinone mono-O,S-acetals is described. These sulfenylation reagents readily react with silyl enolethers or electron rich aromatic compounds to give sulfenylation products under mild conditions. In particular, O,S-acetal 2j, which possesses a pentafluorophenylthio function, is the most effective reagent from the standpoint of the adaptability for various substrates.

本文言語	英語
ページ（範囲）	2434-2441
ページ数	8
ジャーナル	Journal of Organic Chemistry
巻	66
号	7
DOI	https://doi.org/10.1021/jo001710q
出版ステータス	出版済み - 2001/04/06

ASJC Scopus 主題領域

有機化学

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10.1021/jo001710q

引用スタイル

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abstract = "A novel sulfenylation method induced by aromatization of quinone mono-O,S-acetals is described. These sulfenylation reagents readily react with silyl enolethers or electron rich aromatic compounds to give sulfenylation products under mild conditions. In particular, O,S-acetal 2j, which possesses a pentafluorophenylthio function, is the most effective reagent from the standpoint of the adaptability for various substrates.",

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T1 - Facile and efficient sulfenylation method using quinone mono-O,S-acetals under mild conditions

AU - Matsugi, M.

AU - Murata, K.

AU - Gotanda, K.

AU - Nambu, H.

AU - Anilkumar, G.

AU - Matsumoto, K.

AU - Kita, Y.

PY - 2001/4/6

Y1 - 2001/4/6

N2 - A novel sulfenylation method induced by aromatization of quinone mono-O,S-acetals is described. These sulfenylation reagents readily react with silyl enolethers or electron rich aromatic compounds to give sulfenylation products under mild conditions. In particular, O,S-acetal 2j, which possesses a pentafluorophenylthio function, is the most effective reagent from the standpoint of the adaptability for various substrates.

AB - A novel sulfenylation method induced by aromatization of quinone mono-O,S-acetals is described. These sulfenylation reagents readily react with silyl enolethers or electron rich aromatic compounds to give sulfenylation products under mild conditions. In particular, O,S-acetal 2j, which possesses a pentafluorophenylthio function, is the most effective reagent from the standpoint of the adaptability for various substrates.

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U2 - 10.1021/jo001710q

DO - 10.1021/jo001710q

M3 - 学術論文

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SN - 0022-3263

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 7

ER -

Facile and efficient sulfenylation method using quinone mono-O,S-acetals under mild conditions

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