@article{cf79ab2fa80745cf9b494a9a4c196dfc,
title = "Extension of the measurement, assignment, and fit of the rotational spectrum of the two-top molecule methyl acetate",
abstract = "New and previous spectroscopic data were recorded for the two-top molecule methyl acetate using five spectrometers in four different labs: a room temperature chirped-pulse Fourier transform microwave (FTMW) spectrometer in the frequency range from 8.7 to 26.5 GHz, two molecular beam FTMW spectrometers (2-40 GHz), a free jet absorption Stark-modulated spectrometer (60-78 GHz), and a room temperature millimeter-wave spectrometer (44-68 GHz). Approximately 800 new lines with J up to 40 and K up to 16 were assigned. In total, 1603 lines were fitted with 34 parameters using an internal rotation Hamiltonian in the Rho Axis Method (RAM) and the program BELGI-Cs-2tops to standard deviations close to the experimental uncertainties. More precise determinations of the top-top interaction and the J, K dependent parameters were carried out.",
keywords = "BELGI-Cs, Chirped-pulse microwave spectroscopy, Internal rotation, Methyl acetate, Millimeter-wave spectroscopy",
author = "Nguyen, {Ha Vinh Lam} and Isabelle Kleiner and Shipman, {Steven T.} and Yoshiaki Mae and Kazue Hirose and Shota Hatanaka and Kaori Kobayashi",
note = "Funding Information: We thank the PROCOPE project of DAAD for traveling money, Japan Society Promotion Science, Invitation Fellowship Programs for Research in Japan (ID No. S120124), and the ANR-08-BLAN-0054 TopModel project for funds. S.T.S. acknowledges support from the National Science Foundation Division of Chemistry under Grant No. 1111101 (co-funded by MPS/CHE and the Division of Astronomical Sciences ). I.K. and H.V.L.N. would like to thank Dr. Manceron and Dr. Kwabia for their efforts in trying to record the far-infrared spectra at the synchrotron Soleil, St. Aubin, France. ",
year = "2014",
month = may,
doi = "10.1016/j.jms.2014.03.012",
language = "英語",
volume = "299",
pages = "17--21",
journal = "Journal of Molecular Spectroscopy",
issn = "0022-2852",
publisher = "Academic Press Inc.",
}