Extended germa[N]pericyclynes: synthesis and characterization

Hiroki Tanimoto; Taro Fujiwara; Junta Mori; Tomohiko Nagao; Yasuhiro Nishiyama; Tsumoru Morimoto; Shunichiro Ito; Kazuo Tanaka; Yoshiki Chujo; Kiyomi Kakiuchi

doi:10.1039/C6DT04633A

Extended germa[N]pericyclynes: synthesis and characterization

Hiroki Tanimoto^*, Taro Fujiwara, Junta Mori, Tomohiko Nagao, Yasuhiro Nishiyama, Tsumoru Morimoto, Shunichiro Ito, Kazuo Tanaka, Yoshiki Chujo, Kiyomi Kakiuchi

^*この論文の責任著者

生体認識化学研究室

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

11 被引用数 (Scopus)

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We herein describe the syntheses and characterization of extended germa[N]pericyclynes, which are macrocycles composed of germanium-butadiyne units. The obtained novel extended germa[4]-[8]pericyclynes were characterized by X-ray crystallography, UV-Vis spectroscopy, fluorescence and phosphorescence emission spectroscopy, and cyclic voltammetry, and exhibited characteristic absorptions and emissions. Density functional theory (DFT) calculations suggested smaller HOMO-LUMO gap energy compared to that of general germapericyclynes.

本文言語	英語
ページ（範囲）	2281-2288
ページ数	8
ジャーナル	Dalton Transactions
巻	46
号	7
DOI	https://doi.org/10.1039/C6DT04633A
出版ステータス	出版済み - 2017

ASJC Scopus 主題領域

無機化学

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10.1039/C6DT04633A

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title = "Extended germa[N]pericyclynes: synthesis and characterization",

abstract = "We herein describe the syntheses and characterization of extended germa[N]pericyclynes, which are macrocycles composed of germanium-butadiyne units. The obtained novel extended germa[4]-[8]pericyclynes were characterized by X-ray crystallography, UV-Vis spectroscopy, fluorescence and phosphorescence emission spectroscopy, and cyclic voltammetry, and exhibited characteristic absorptions and emissions. Density functional theory (DFT) calculations suggested smaller HOMO-LUMO gap energy compared to that of general germapericyclynes.",

author = "Hiroki Tanimoto and Taro Fujiwara and Junta Mori and Tomohiko Nagao and Yasuhiro Nishiyama and Tsumoru Morimoto and Shunichiro Ito and Kazuo Tanaka and Yoshiki Chujo and Kiyomi Kakiuchi",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/C6DT04633A",

language = "英語",

volume = "46",

pages = "2281--2288",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Extended germa[N]pericyclynes

T2 - synthesis and characterization

AU - Tanimoto, Hiroki

AU - Fujiwara, Taro

AU - Mori, Junta

AU - Nagao, Tomohiko

AU - Nishiyama, Yasuhiro

AU - Morimoto, Tsumoru

AU - Ito, Shunichiro

AU - Tanaka, Kazuo

AU - Chujo, Yoshiki

AU - Kakiuchi, Kiyomi

PY - 2017

Y1 - 2017

N2 - We herein describe the syntheses and characterization of extended germa[N]pericyclynes, which are macrocycles composed of germanium-butadiyne units. The obtained novel extended germa[4]-[8]pericyclynes were characterized by X-ray crystallography, UV-Vis spectroscopy, fluorescence and phosphorescence emission spectroscopy, and cyclic voltammetry, and exhibited characteristic absorptions and emissions. Density functional theory (DFT) calculations suggested smaller HOMO-LUMO gap energy compared to that of general germapericyclynes.

AB - We herein describe the syntheses and characterization of extended germa[N]pericyclynes, which are macrocycles composed of germanium-butadiyne units. The obtained novel extended germa[4]-[8]pericyclynes were characterized by X-ray crystallography, UV-Vis spectroscopy, fluorescence and phosphorescence emission spectroscopy, and cyclic voltammetry, and exhibited characteristic absorptions and emissions. Density functional theory (DFT) calculations suggested smaller HOMO-LUMO gap energy compared to that of general germapericyclynes.

UR - http://www.scopus.com/inward/record.url?scp=85013276797&partnerID=8YFLogxK

U2 - 10.1039/C6DT04633A

DO - 10.1039/C6DT04633A

M3 - 学術論文

C2 - 28133678

AN - SCOPUS:85013276797

SN - 1477-9226

VL - 46

SP - 2281

EP - 2288

JO - Dalton Transactions

JF - Dalton Transactions

IS - 7

ER -

Extended germa[N]pericyclynes: synthesis and characterization

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