Endoperoxidation of 9,10-bis(1-hydroxyalkyl)-anthracenes and successive formation of 9,10-anthraquinone under Grignard reaction conditions

Shigeyasu Kuroda; Mitsunori Oda; Hiroki Syumiya; Shah M.I. Shaheen; Ryuta Miyatake; Teruhiko Nishikawa; Akiko Yoneda; Tokiko Tanaka; Masaru Mouri; Mayumi Kyogoku

doi:10.3987/COM-03-S(P)24

Endoperoxidation of 9,10-bis(1-hydroxyalkyl)-anthracenes and successive formation of 9,10-anthraquinone under Grignard reaction conditions

Shigeyasu Kuroda^*, Mitsunori Oda, Hiroki Syumiya, Shah M.I. Shaheen, Ryuta Miyatake, Teruhiko Nishikawa, Akiko Yoneda, Tokiko Tanaka, Masaru Mouri, Mayumi Kyogoku

^*この論文の責任著者

環境安全推進センター

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

6 被引用数 (Scopus)

抄録

The reaction of anthracene-9,10-carboaldehyde with various Grignard reagents under ambient conditions gave 9,10-bis(1-hydroxyalkyl)anthracene-9,10-peroxides and 9,10-anthraquinone as the first example. The endoperoxidation of 9,10-bis(1-hydroxyalkyl)anthracenes was assisted by the lone paired electron of oxygen in the side chain, and the endoperoxides were transformed to anthraquinone by the Grignard reagents.

本文言語	英語
ページ（範囲）	153-159
ページ数	7
ジャーナル	Heterocycles
巻	62
DOI	https://doi.org/10.3987/COM-03-S(P)24
出版ステータス	出版済み - 2004/01/01

ASJC Scopus 主題領域

分析化学
薬理学
有機化学

文献へのアクセス

10.3987/COM-03-S(P)24

フィンガープリント

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引用スタイル

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title = "Endoperoxidation of 9,10-bis(1-hydroxyalkyl)-anthracenes and successive formation of 9,10-anthraquinone under Grignard reaction conditions",

abstract = "The reaction of anthracene-9,10-carboaldehyde with various Grignard reagents under ambient conditions gave 9,10-bis(1-hydroxyalkyl)anthracene-9,10-peroxides and 9,10-anthraquinone as the first example. The endoperoxidation of 9,10-bis(1-hydroxyalkyl)anthracenes was assisted by the lone paired electron of oxygen in the side chain, and the endoperoxides were transformed to anthraquinone by the Grignard reagents.",

author = "Shigeyasu Kuroda and Mitsunori Oda and Hiroki Syumiya and Shaheen, {Shah M.I.} and Ryuta Miyatake and Teruhiko Nishikawa and Akiko Yoneda and Tokiko Tanaka and Masaru Mouri and Mayumi Kyogoku",

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doi = "10.3987/COM-03-S(P)24",

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T1 - Endoperoxidation of 9,10-bis(1-hydroxyalkyl)-anthracenes and successive formation of 9,10-anthraquinone under Grignard reaction conditions

AU - Kuroda, Shigeyasu

AU - Oda, Mitsunori

AU - Syumiya, Hiroki

AU - Shaheen, Shah M.I.

AU - Miyatake, Ryuta

AU - Nishikawa, Teruhiko

AU - Yoneda, Akiko

AU - Tanaka, Tokiko

AU - Mouri, Masaru

AU - Kyogoku, Mayumi

PY - 2004/1/1

Y1 - 2004/1/1

N2 - The reaction of anthracene-9,10-carboaldehyde with various Grignard reagents under ambient conditions gave 9,10-bis(1-hydroxyalkyl)anthracene-9,10-peroxides and 9,10-anthraquinone as the first example. The endoperoxidation of 9,10-bis(1-hydroxyalkyl)anthracenes was assisted by the lone paired electron of oxygen in the side chain, and the endoperoxides were transformed to anthraquinone by the Grignard reagents.

AB - The reaction of anthracene-9,10-carboaldehyde with various Grignard reagents under ambient conditions gave 9,10-bis(1-hydroxyalkyl)anthracene-9,10-peroxides and 9,10-anthraquinone as the first example. The endoperoxidation of 9,10-bis(1-hydroxyalkyl)anthracenes was assisted by the lone paired electron of oxygen in the side chain, and the endoperoxides were transformed to anthraquinone by the Grignard reagents.

UR - http://www.scopus.com/inward/record.url?scp=0347090303&partnerID=8YFLogxK

U2 - 10.3987/COM-03-S(P)24

DO - 10.3987/COM-03-S(P)24

M3 - 学術論文

AN - SCOPUS:0347090303

SN - 0385-5414

VL - 62

SP - 153

EP - 159

JO - Heterocycles

JF - Heterocycles

ER -