抄録
A chiral 1,1′-bi-2-naphthol (BINOL)-containing pyridine-acetylene-phenol macrocycle and a pyridine-BINOL alternating macrocycle were developed for enantioselective recognition of saccharides. In solid-liquid extraction of native saccharides, these macrocycles selectively extracted one enantiomer from each of a racemic mixture of d/l-fructose, d/l-glucose, and d/l-mannose into a lipophilic solvent. This is the first example in which native saccharides, especially such important hexoses, were enantioselectively extracted with artificial host molecules.
| 本文言語 | 英語 |
|---|---|
| ページ（範囲） | 6202-6207 |
| ページ数 | 6 |
| ジャーナル | Organic Letters |
| 巻 | 21 |
| 号 | 16 |
| DOI | |
| 出版ステータス | 出版済み - 2019/08/16 |
ASJC Scopus 主題領域
- 生化学
- 物理化学および理論化学
- 有機化学