Effects of π-conjugation on the solid-state photoresponsive coloring behavior of bipyridine-boronium complexes

Junro Yoshino; Yoshito Hirono; Ryota Akahane; Hiroyuki Higuchi; Naoto Hayashi

doi:10.1039/d0pp00296h

Effects of π-conjugation on the solid-state photoresponsive coloring behavior of bipyridine-boronium complexes

Junro Yoshino^*, Yoshito Hirono, Ryota Akahane, Hiroyuki Higuchi, Naoto Hayashi

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

2 被引用数 (Scopus)

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Solid-state photoinduced coloring of boronium complexes consisting of 9-borabicyclononane and 2,2′-bipyridine with π-conjugated substituents at the 4,4′- or 5,5′-positions was investigated. The substitution position affected the highest occupied molecular orbital distribution and determined the coloring capability. The 4,4′-substituted complexes exhibited coloration upon irradiation, whereas most of the 5,5′-substituted complexes did not.

本文言語	英語
ページ（範囲）	1517-1521
ページ数	5
ジャーナル	Photochemical and Photobiological Sciences
巻	19
号	11
DOI	https://doi.org/10.1039/d0pp00296h
出版ステータス	出版済み - 2020

ASJC Scopus 主題領域

物理化学および理論化学

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10.1039/d0pp00296h

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abstract = "Solid-state photoinduced coloring of boronium complexes consisting of 9-borabicyclononane and 2,2′-bipyridine with π-conjugated substituents at the 4,4′- or 5,5′-positions was investigated. The substitution position affected the highest occupied molecular orbital distribution and determined the coloring capability. The 4,4′-substituted complexes exhibited coloration upon irradiation, whereas most of the 5,5′-substituted complexes did not.",

author = "Junro Yoshino and Yoshito Hirono and Ryota Akahane and Hiroyuki Higuchi and Naoto Hayashi",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and Owner Societies.",

year = "2020",

doi = "10.1039/d0pp00296h",

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T1 - Effects of π-conjugation on the solid-state photoresponsive coloring behavior of bipyridine-boronium complexes

AU - Yoshino, Junro

AU - Hirono, Yoshito

AU - Akahane, Ryota

AU - Higuchi, Hiroyuki

AU - Hayashi, Naoto

N1 - Publisher Copyright: © The Royal Society of Chemistry and Owner Societies.

PY - 2020

Y1 - 2020

N2 - Solid-state photoinduced coloring of boronium complexes consisting of 9-borabicyclononane and 2,2′-bipyridine with π-conjugated substituents at the 4,4′- or 5,5′-positions was investigated. The substitution position affected the highest occupied molecular orbital distribution and determined the coloring capability. The 4,4′-substituted complexes exhibited coloration upon irradiation, whereas most of the 5,5′-substituted complexes did not.

AB - Solid-state photoinduced coloring of boronium complexes consisting of 9-borabicyclononane and 2,2′-bipyridine with π-conjugated substituents at the 4,4′- or 5,5′-positions was investigated. The substitution position affected the highest occupied molecular orbital distribution and determined the coloring capability. The 4,4′-substituted complexes exhibited coloration upon irradiation, whereas most of the 5,5′-substituted complexes did not.

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U2 - 10.1039/d0pp00296h

DO - 10.1039/d0pp00296h

M3 - 学術論文

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AN - SCOPUS:85096152215

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JO - Photochemical and Photobiological Sciences

JF - Photochemical and Photobiological Sciences

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ER -

Effects of π-conjugation on the solid-state photoresponsive coloring behavior of bipyridine-boronium complexes

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