Divergent synthesis of (+)-tanikolide and its analogues employing stereoselective rhodium(II)-catalyzed reaction

Keyphrases

• Stereoselectivity 100%
• Dirhodium Complex 100%
• Divergent Synthesis 100%
• Rhodium Catalysis 100%
• Methanol 50%
• Lactones 50%
• Tetrahydrofuran 50%
• Long Side Chain 50%
• Lactonization 50%
• Catalyzed Reaction 50%
• Ring Expansion 50%
• 2,3-Sigmatropic Rearrangement 50%
• N-heterocyclic Carbenes 50%
• Oxonium Ylide 50%
• 2-Iodobenzamides 50%
• Oxidative Cleavage 50%
• Quaternary chiral Center 50%
• High Flexibility 50%
• Analog Synthesis 50%

Chemistry

• Rhodium 100%
• Catalysis 100%
• Methanol 50%
• Tetrahydrofuran 50%
• Lactone 50%
• Ring Expansion 50%
• Oxonium Ylide 50%
• N-Heterocyclic Carbene 50%
• Oxidative Elimination Reaction 50%
• formation 50%
• lactonization 50%