Crystal structure of S-n-octyl 3-(1-phenylethyl-idene)dithiocarbazate and of its bis-chelated nickel(II) complex

Sultana Shakila Khan, Md Belayet Hossain Howlader*, Md Chanmiya Sheikh, Ryuta Miyatake, Ennio Zangrando, Md Rezaul Haque Ansary

*この論文の責任著者

研究成果: ジャーナルへの寄稿学術論文査読

2 被引用数 (Scopus)

抄録

The nitrogen–sulfur Schiff base proligand S-n-octyl 3-(1-phenylethylidene)di-thiocarbazate, C17H26N2S2 (HL), was prepared by reaction of S-octyl dithiocarbamate with acetophenone. Treatment of HL with nickel acetate yielded the complex bis[S-n-octyl 3-(1-phenylethylidene)dithiocarbazato]nickel(II), [Ni(C17H25N2S2)2] (NiL2), which was shown to adopt a tetrahedrally distorted cis-square-planar coordination geometry, with the NiSN planes of the two ligands forming a dihedral angle of 21.66 (6). Changes in the geometry of the L ligand upon chelation of Ni2+ are described, involving a ca 180 rotation around the N(azomethine)—C(thiolate) bond.

本文言語英語
ページ(範囲)1137-1141
ページ数5
ジャーナルActa Crystallographica Section E: Crystallographic Communications
79
Pt 12
DOI
出版ステータス出版済み - 2023/11/14

ASJC Scopus 主題領域

  • 化学一般
  • 材料科学一般
  • 凝縮系物理学

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