Crystal structure of S-n-octyl 3-(1-phenylethyl-idene)dithiocarbazate and of its bis-chelated nickel(II) complex

Sultana Shakila Khan; Md Belayet Hossain Howlader; Md Chanmiya Sheikh; Ryuta Miyatake; Ennio Zangrando; Md Rezaul Haque Ansary

doi:10.1107/S2056989023009726

Crystal structure of S-n-octyl 3-(1-phenylethyl-idene)dithiocarbazate and of its bis-chelated nickel(II) complex

Sultana Shakila Khan, Md Belayet Hossain Howlader^*, Md Chanmiya Sheikh, Ryuta Miyatake, Ennio Zangrando, Md Rezaul Haque Ansary

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研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

2 被引用数 (Scopus)

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The nitrogen–sulfur Schiff base proligand S-n-octyl 3-(1-phenylethylidene)di-thiocarbazate, C₁₇H₂₆N₂S₂ (HL), was prepared by reaction of S-octyl dithiocarbamate with acetophenone. Treatment of HL with nickel acetate yielded the complex bis[S-n-octyl 3-(1-phenylethylidene)dithiocarbazato]nickel(II), [Ni(C₁₇H₂₅N₂S₂)₂] (NiL₂), which was shown to adopt a tetrahedrally distorted cis-square-planar coordination geometry, with the NiSN planes of the two ligands forming a dihedral angle of 21.66 (6)^◦. Changes in the geometry of the L ligand upon chelation of Ni²⁺ are described, involving a ca 180^◦ rotation around the N(azomethine)—C(thiolate) bond.

本文言語	英語
ページ（範囲）	1137-1141
ページ数	5
ジャーナル	Acta Crystallographica Section E: Crystallographic Communications
巻	79
号	Pt 12
DOI	https://doi.org/10.1107/S2056989023009726
出版ステータス	出版済み - 2023/11/14

ASJC Scopus 主題領域

化学一般
材料科学一般
凝縮系物理学

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10.1107/S2056989023009726

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@article{6ce829348cde446e806046df2bcf8c99,

title = "Crystal structure of S-n-octyl 3-(1-phenylethyl-idene)dithiocarbazate and of its bis-chelated nickel(II) complex",

abstract = "The nitrogen–sulfur Schiff base proligand S-n-octyl 3-(1-phenylethylidene)di-thiocarbazate, C17H26N2S2 (HL), was prepared by reaction of S-octyl dithiocarbamate with acetophenone. Treatment of HL with nickel acetate yielded the complex bis[S-n-octyl 3-(1-phenylethylidene)dithiocarbazato]nickel(II), [Ni(C17H25N2S2)2] (NiL2), which was shown to adopt a tetrahedrally distorted cis-square-planar coordination geometry, with the NiSN planes of the two ligands forming a dihedral angle of 21.66 (6)◦. Changes in the geometry of the L ligand upon chelation of Ni2+ are described, involving a ca 180◦ rotation around the N(azomethine)—C(thiolate) bond.",

keywords = "Ni complex, cis configuration complex, crystal structure, dithiocarbazate ligand, octyl alkyl chain",

author = "Khan, {Sultana Shakila} and Howlader, {Md Belayet Hossain} and Sheikh, {Md Chanmiya} and Ryuta Miyatake and Ennio Zangrando and Ansary, {Md Rezaul Haque}",

year = "2023",

month = nov,

day = "14",

doi = "10.1107/S2056989023009726",

language = "英語",

volume = "79",

pages = "1137--1141",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography",

number = "Pt 12",

}

Crystal structure of S-n-octyl 3-(1-phenylethyl-idene)dithiocarbazate and of its bis-chelated nickel(II) complex. / Khan, Sultana Shakila; Howlader, Md Belayet Hossain; Sheikh, Md Chanmiya その他.
In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 79, No. Pt 12, 14.11.2023, p. 1137-1141.

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

TY - JOUR

T1 - Crystal structure of S-n-octyl 3-(1-phenylethyl-idene)dithiocarbazate and of its bis-chelated nickel(II) complex

AU - Khan, Sultana Shakila

AU - Howlader, Md Belayet Hossain

AU - Sheikh, Md Chanmiya

AU - Miyatake, Ryuta

AU - Zangrando, Ennio

AU - Ansary, Md Rezaul Haque

PY - 2023/11/14

Y1 - 2023/11/14

N2 - The nitrogen–sulfur Schiff base proligand S-n-octyl 3-(1-phenylethylidene)di-thiocarbazate, C17H26N2S2 (HL), was prepared by reaction of S-octyl dithiocarbamate with acetophenone. Treatment of HL with nickel acetate yielded the complex bis[S-n-octyl 3-(1-phenylethylidene)dithiocarbazato]nickel(II), [Ni(C17H25N2S2)2] (NiL2), which was shown to adopt a tetrahedrally distorted cis-square-planar coordination geometry, with the NiSN planes of the two ligands forming a dihedral angle of 21.66 (6)◦. Changes in the geometry of the L ligand upon chelation of Ni2+ are described, involving a ca 180◦ rotation around the N(azomethine)—C(thiolate) bond.

AB - The nitrogen–sulfur Schiff base proligand S-n-octyl 3-(1-phenylethylidene)di-thiocarbazate, C17H26N2S2 (HL), was prepared by reaction of S-octyl dithiocarbamate with acetophenone. Treatment of HL with nickel acetate yielded the complex bis[S-n-octyl 3-(1-phenylethylidene)dithiocarbazato]nickel(II), [Ni(C17H25N2S2)2] (NiL2), which was shown to adopt a tetrahedrally distorted cis-square-planar coordination geometry, with the NiSN planes of the two ligands forming a dihedral angle of 21.66 (6)◦. Changes in the geometry of the L ligand upon chelation of Ni2+ are described, involving a ca 180◦ rotation around the N(azomethine)—C(thiolate) bond.

KW - Ni complex

KW - cis configuration complex

KW - crystal structure

KW - dithiocarbazate ligand

KW - octyl alkyl chain

UR - http://www.scopus.com/inward/record.url?scp=85179414939&partnerID=8YFLogxK

U2 - 10.1107/S2056989023009726

DO - 10.1107/S2056989023009726

M3 - 学術論文

C2 - 38313117

AN - SCOPUS:85179414939

SN - 2056-9890

VL - 79

SP - 1137

EP - 1141

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

IS - Pt 12

ER -

Crystal structure of S-n-octyl 3-(1-phenylethyl-idene)dithiocarbazate and of its bis-chelated nickel(II) complex

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