TY - JOUR
T1 - Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ2N 3,S}nickel(II)
AU - Khan, Sultana Shakila
AU - Howlader, Md Belayet Hossain
AU - Sheikh, Md Chanmiya
AU - Miyatake, Ryuta
AU - Zangrando, Ennio
N1 - Publisher Copyright:
© 2023 International Union of Crystallography. All rights reserved.
PY - 2023/7/11
Y1 - 2023/7/11
N2 - In the title complex, [Ni(C14H21N2S3)2], the nickel(II) atom is located on a crystallographic inversion center and exhibits a square-planar coordination environment, being coordinated by two negatively charged N,S-chelating ligands in a trans configuration. In the crystal, the non-H atoms of the complex are practically coplanar (r.m.s. deviation of fitted atoms = 0.135 Å), and the angle between the thienyl and the chelating rings is 6.7 (1)°. The molecules stack at a distance of 3.623 (2) Å along the b-axis direction.
AB - In the title complex, [Ni(C14H21N2S3)2], the nickel(II) atom is located on a crystallographic inversion center and exhibits a square-planar coordination environment, being coordinated by two negatively charged N,S-chelating ligands in a trans configuration. In the crystal, the non-H atoms of the complex are practically coplanar (r.m.s. deviation of fitted atoms = 0.135 Å), and the angle between the thienyl and the chelating rings is 6.7 (1)°. The molecules stack at a distance of 3.623 (2) Å along the b-axis direction.
KW - crystal structure
KW - dithiocarbazato ligand
KW - nickel(II) complex
UR - http://www.scopus.com/inward/record.url?scp=85169590713&partnerID=8YFLogxK
U2 - 10.1107/S2056989023005935
DO - 10.1107/S2056989023005935
M3 - 学術論文
C2 - 37601399
AN - SCOPUS:85169590713
SN - 2056-9890
VL - 79
SP - 714
EP - 717
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
ER -