Copper(ii)/phenanthroline-mediated CD-enhancement and chiral memory effect on a meta-ethynylpyridine oligomer

Shunsuke Takashima; Hajime Abe; Masahiko Inouye

doi:10.1039/c2cc00063f

Copper(ii)/phenanthroline-mediated CD-enhancement and chiral memory effect on a meta-ethynylpyridine oligomer

Shunsuke Takashima, Hajime Abe^*, Masahiko Inouye

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研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

32 被引用数 (Scopus)

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Meta-Ethynylpyridine 18-mer associates with octyl β-d-glucopyranoside to show an induced circular dichroism (CD) band at around 337 nm in CH₂Cl₂. The addition of copper(ii) triflate and o-phenanthroline enhanced the CD band. Even when an equimolar amount of β-l-glucopyranoside was added to make the system racemic, the CD was memorized and remained for several weeks.

本文言語	英語
ページ（範囲）	3330-3332
ページ数	3
ジャーナル	Chemical Communications
巻	48
号	27
DOI	https://doi.org/10.1039/c2cc00063f
出版ステータス	出版済み - 2012/03/05

ASJC Scopus 主題領域

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学一般
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/c2cc00063f

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abstract = "Meta-Ethynylpyridine 18-mer associates with octyl β-d-glucopyranoside to show an induced circular dichroism (CD) band at around 337 nm in CH2Cl2. The addition of copper(ii) triflate and o-phenanthroline enhanced the CD band. Even when an equimolar amount of β-l-glucopyranoside was added to make the system racemic, the CD was memorized and remained for several weeks.",

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AU - Takashima, Shunsuke

AU - Abe, Hajime

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PY - 2012/3/5

Y1 - 2012/3/5

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AB - Meta-Ethynylpyridine 18-mer associates with octyl β-d-glucopyranoside to show an induced circular dichroism (CD) band at around 337 nm in CH2Cl2. The addition of copper(ii) triflate and o-phenanthroline enhanced the CD band. Even when an equimolar amount of β-l-glucopyranoside was added to make the system racemic, the CD was memorized and remained for several weeks.

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DO - 10.1039/c2cc00063f

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Copper(ii)/phenanthroline-mediated CD-enhancement and chiral memory effect on a meta-ethynylpyridine oligomer

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