Cooperative effect of spacer and Lewis base on highly reversible spectral changes of the octaethylporphyrin chromatic system in sensitivity, stability, and visibility to trifluoroacetic acid

Hideto Kempe; Junya Yamamoto; Miki Ishida; Nobutomo Takahashi; Junro Yoshino; Naoto Hayashi; Hiroyuki Higuchi

doi:10.1246/bcsj.20160176

Cooperative effect of spacer and Lewis base on highly reversible spectral changes of the octaethylporphyrin chromatic system in sensitivity, stability, and visibility to trifluoroacetic acid

Hideto Kempe, Junya Yamamoto, Miki Ishida, Nobutomo Takahashi, Junro Yoshino, Naoto Hayashi, Hiroyuki Higuchi^*

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

2 被引用数 (Scopus)

抄録

The diacetylene-group connected chromatic system of [octaethylporphyrin]-[spacer]-[Lewis base] triads (OEP-SPC-LB) was conclusively studied, in which a trigger-like interaction of the terminal LB with trifluoroacetic acid (TFA) dramatically affects the inherent electronic properties of OEP. The ¹HNMR, IR, and electronic absorption spectral properties of these OEP derivatives were examined, and were contemplated in view of a cooperative effect of SPC and LB on their OEP nucleus. Based on the results from this study, the structural elements for molecular design will be proposed in order to improve their reversible spectral changes between neutral and acidic media in terms of sensitivity, stability, and visibility to TFA.

本文言語	英語
ページ（範囲）	1233-1244
ページ数	12
ジャーナル	Bulletin of the Chemical Society of Japan
巻	89
号	10
DOI	https://doi.org/10.1246/bcsj.20160176
出版ステータス	出版済み - 2016

ASJC Scopus 主題領域

化学一般

文献へのアクセス

10.1246/bcsj.20160176

フィンガープリント

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引用スタイル

Kempe, H., Yamamoto, J., Ishida, M., Takahashi, N., Yoshino, J., Hayashi, N., & Higuchi, H. (2016). Cooperative effect of spacer and Lewis base on highly reversible spectral changes of the octaethylporphyrin chromatic system in sensitivity, stability, and visibility to trifluoroacetic acid. Bulletin of the Chemical Society of Japan, 89(10), 1233-1244. https://doi.org/10.1246/bcsj.20160176

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title = "Cooperative effect of spacer and Lewis base on highly reversible spectral changes of the octaethylporphyrin chromatic system in sensitivity, stability, and visibility to trifluoroacetic acid",

abstract = "The diacetylene-group connected chromatic system of [octaethylporphyrin]-[spacer]-[Lewis base] triads (OEP-SPC-LB) was conclusively studied, in which a trigger-like interaction of the terminal LB with trifluoroacetic acid (TFA) dramatically affects the inherent electronic properties of OEP. The 1HNMR, IR, and electronic absorption spectral properties of these OEP derivatives were examined, and were contemplated in view of a cooperative effect of SPC and LB on their OEP nucleus. Based on the results from this study, the structural elements for molecular design will be proposed in order to improve their reversible spectral changes between neutral and acidic media in terms of sensitivity, stability, and visibility to TFA.",

author = "Hideto Kempe and Junya Yamamoto and Miki Ishida and Nobutomo Takahashi and Junro Yoshino and Naoto Hayashi and Hiroyuki Higuchi",

note = "Publisher Copyright: {\textcopyright} 2016 The Chemical Society of Japan.",

year = "2016",

doi = "10.1246/bcsj.20160176",

language = "英語",

volume = "89",

pages = "1233--1244",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Oxford University Press",

number = "10",

}

Kempe, H, Yamamoto, J, Ishida, M, Takahashi, N, Yoshino, J , Hayashi, N & Higuchi, H 2016, 'Cooperative effect of spacer and Lewis base on highly reversible spectral changes of the octaethylporphyrin chromatic system in sensitivity, stability, and visibility to trifluoroacetic acid', Bulletin of the Chemical Society of Japan, vol. 89, no. 10, pp. 1233-1244. https://doi.org/10.1246/bcsj.20160176

Cooperative effect of spacer and Lewis base on highly reversible spectral changes of the octaethylporphyrin chromatic system in sensitivity, stability, and visibility to trifluoroacetic acid. / Kempe, Hideto; Yamamoto, Junya; Ishida, Miki その他.
In: Bulletin of the Chemical Society of Japan, Vol. 89, No. 10, 2016, p. 1233-1244.

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

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T1 - Cooperative effect of spacer and Lewis base on highly reversible spectral changes of the octaethylporphyrin chromatic system in sensitivity, stability, and visibility to trifluoroacetic acid

AU - Kempe, Hideto

AU - Yamamoto, Junya

AU - Ishida, Miki

AU - Takahashi, Nobutomo

AU - Yoshino, Junro

AU - Hayashi, Naoto

AU - Higuchi, Hiroyuki

PY - 2016

Y1 - 2016

N2 - The diacetylene-group connected chromatic system of [octaethylporphyrin]-[spacer]-[Lewis base] triads (OEP-SPC-LB) was conclusively studied, in which a trigger-like interaction of the terminal LB with trifluoroacetic acid (TFA) dramatically affects the inherent electronic properties of OEP. The 1HNMR, IR, and electronic absorption spectral properties of these OEP derivatives were examined, and were contemplated in view of a cooperative effect of SPC and LB on their OEP nucleus. Based on the results from this study, the structural elements for molecular design will be proposed in order to improve their reversible spectral changes between neutral and acidic media in terms of sensitivity, stability, and visibility to TFA.

AB - The diacetylene-group connected chromatic system of [octaethylporphyrin]-[spacer]-[Lewis base] triads (OEP-SPC-LB) was conclusively studied, in which a trigger-like interaction of the terminal LB with trifluoroacetic acid (TFA) dramatically affects the inherent electronic properties of OEP. The 1HNMR, IR, and electronic absorption spectral properties of these OEP derivatives were examined, and were contemplated in view of a cooperative effect of SPC and LB on their OEP nucleus. Based on the results from this study, the structural elements for molecular design will be proposed in order to improve their reversible spectral changes between neutral and acidic media in terms of sensitivity, stability, and visibility to TFA.

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