Chirality transfer in the palladium(0)-catalyzed cyclization of 3-oxo-8,9-dihydroxytetradeca-1,6-diene derivatives into 2-methylenecyclopentanones

Kazuhiko Togashi; Masahiko Terakado; Masahiro Miyazawa; Keiji Yamamoto; Takashi Takahashi

doi:10.1016/S0040-4039(00)76900-0

Chirality transfer in the palladium(0)-catalyzed cyclization of 3-oxo-8,9-dihydroxytetradeca-1,6-diene derivatives into 2-methylenecyclopentanones

Kazuhiko Togashi^*, Masahiko Terakado, Masahiro Miyazawa, Keiji Yamamoto, Takashi Takahashi

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

10 被引用数 (Scopus)

抄録

Pd(0)-catalyzed cyclizations of four diastereomeric 3-oxo-8,9-dihydroxytetradeca-1,6-diene derivatives were carried out to give 2-methylenecyclopentanones with stereospecific 1,3-chirality transfer in up to 95% overall inversion of stereochemistry, one of which contains a correct ω-side chain to be the Stork's intermediate for prostaglandins.

本文言語	英語
ページ（範囲）	3333-3336
ページ数	4
ジャーナル	Tetrahedron Letters
巻	35
号	20
DOI	https://doi.org/10.1016/S0040-4039(00)76900-0
出版ステータス	出版済み - 1994/05/16

ASJC Scopus 主題領域

生化学
創薬
有機化学

文献へのアクセス

10.1016/S0040-4039(00)76900-0

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引用スタイル

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title = "Chirality transfer in the palladium(0)-catalyzed cyclization of 3-oxo-8,9-dihydroxytetradeca-1,6-diene derivatives into 2-methylenecyclopentanones",

abstract = "Pd(0)-catalyzed cyclizations of four diastereomeric 3-oxo-8,9-dihydroxytetradeca-1,6-diene derivatives were carried out to give 2-methylenecyclopentanones with stereospecific 1,3-chirality transfer in up to 95% overall inversion of stereochemistry, one of which contains a correct ω-side chain to be the Stork's intermediate for prostaglandins.",

author = "Kazuhiko Togashi and Masahiko Terakado and Masahiro Miyazawa and Keiji Yamamoto and Takashi Takahashi",

year = "1994",

month = may,

day = "16",

doi = "10.1016/S0040-4039(00)76900-0",

language = "英語",

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pages = "3333--3336",

journal = "Tetrahedron Letters",

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T1 - Chirality transfer in the palladium(0)-catalyzed cyclization of 3-oxo-8,9-dihydroxytetradeca-1,6-diene derivatives into 2-methylenecyclopentanones

AU - Togashi, Kazuhiko

AU - Terakado, Masahiko

AU - Miyazawa, Masahiro

AU - Yamamoto, Keiji

AU - Takahashi, Takashi

PY - 1994/5/16

Y1 - 1994/5/16

N2 - Pd(0)-catalyzed cyclizations of four diastereomeric 3-oxo-8,9-dihydroxytetradeca-1,6-diene derivatives were carried out to give 2-methylenecyclopentanones with stereospecific 1,3-chirality transfer in up to 95% overall inversion of stereochemistry, one of which contains a correct ω-side chain to be the Stork's intermediate for prostaglandins.

AB - Pd(0)-catalyzed cyclizations of four diastereomeric 3-oxo-8,9-dihydroxytetradeca-1,6-diene derivatives were carried out to give 2-methylenecyclopentanones with stereospecific 1,3-chirality transfer in up to 95% overall inversion of stereochemistry, one of which contains a correct ω-side chain to be the Stork's intermediate for prostaglandins.

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DO - 10.1016/S0040-4039(00)76900-0

M3 - 学術論文

AN - SCOPUS:0028227841

SN - 0040-4039

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EP - 3336

JO - Tetrahedron Letters

JF - Tetrahedron Letters

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