Chiral distortion of Di(μ-sulfido)-bis[oxomolybdenum(V)] complexes of a hexadentate ligand N,N,N′,N′-tetrakis(2-pyridylmethyl)-R- propylenediamine and its analogs

Hai Ying Jin; Ryoichi Hazama; Mikio Yamasaki; Keisuke Umakoshi; Kiyoshi Tsuge; Yoichi Sasaki

doi:10.1246/bcsj.78.2161

Chiral distortion of Di(μ-sulfido)-bis[oxomolybdenum(V)] complexes of a hexadentate ligand N,N,N′,N′-tetrakis(2-pyridylmethyl)-R- propylenediamine and its analogs

Hai Ying Jin, Ryoichi Hazama, Mikio Yamasaki, Keisuke Umakoshi^*, Kiyoshi Tsuge, Yoichi Sasaki

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

2 被引用数 (Scopus)

抄録

Chiral distortion of the basal four pyridyl nitrogen donors of the titled complex [Mo₂(O)₂(μ-S)₂{μ-N,N,N′, N′-tetrakis(2-pyridylmethyl)-R-propylenediamine}]²⁺ has been found to be the reverse to that of the corresponding di-μ-oxo complex, on the basis of the inverse pattern of the circular dichroism spectra. Asymmetric distortion of the dimolybdenum(III) dimer [Mo₂(μ-OH) ₂(μ-CH₃COO){μ-N,N,N′,N′-tetrakis(2- pyridylmethyl)ethylenediamine}]³⁺ has also been discussed.

本文言語	英語
ページ（範囲）	2161-2163
ページ数	3
ジャーナル	Bulletin of the Chemical Society of Japan
巻	78
号	12
DOI	https://doi.org/10.1246/bcsj.78.2161
出版ステータス	出版済み - 2005

ASJC Scopus 主題領域

化学一般

文献へのアクセス

10.1246/bcsj.78.2161

フィンガープリント

「Chiral distortion of Di(μ-sulfido)-bis[oxomolybdenum(V)] complexes of a hexadentate ligand N,N,N′,N′-tetrakis(2-pyridylmethyl)-R- propylenediamine and its analogs」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{0396df3142bd4487aae5c8da209d140b,

title = "Chiral distortion of Di(μ-sulfido)-bis[oxomolybdenum(V)] complexes of a hexadentate ligand N,N,N′,N′-tetrakis(2-pyridylmethyl)-R- propylenediamine and its analogs",

abstract = "Chiral distortion of the basal four pyridyl nitrogen donors of the titled complex [Mo2(O)2(μ-S)2{μ-N,N,N′, N′-tetrakis(2-pyridylmethyl)-R-propylenediamine}]2+ has been found to be the reverse to that of the corresponding di-μ-oxo complex, on the basis of the inverse pattern of the circular dichroism spectra. Asymmetric distortion of the dimolybdenum(III) dimer [Mo2(μ-OH) 2(μ-CH3COO){μ-N,N,N′,N′-tetrakis(2- pyridylmethyl)ethylenediamine}]3+ has also been discussed.",

author = "Jin, {Hai Ying} and Ryoichi Hazama and Mikio Yamasaki and Keisuke Umakoshi and Kiyoshi Tsuge and Yoichi Sasaki",

year = "2005",

doi = "10.1246/bcsj.78.2161",

language = "英語",

volume = "78",

pages = "2161--2163",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Oxford University Press",

number = "12",

}

Chiral distortion of Di(μ-sulfido)-bis[oxomolybdenum(V)] complexes of a hexadentate ligand N,N,N′,N′-tetrakis(2-pyridylmethyl)-R- propylenediamine and its analogs. / Jin, Hai Ying; Hazama, Ryoichi; Yamasaki, Mikio その他.
In: Bulletin of the Chemical Society of Japan, Vol. 78, No. 12, 2005, p. 2161-2163.

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

TY - JOUR

T1 - Chiral distortion of Di(μ-sulfido)-bis[oxomolybdenum(V)] complexes of a hexadentate ligand N,N,N′,N′-tetrakis(2-pyridylmethyl)-R- propylenediamine and its analogs

AU - Jin, Hai Ying

AU - Hazama, Ryoichi

AU - Yamasaki, Mikio

AU - Umakoshi, Keisuke

AU - Tsuge, Kiyoshi

AU - Sasaki, Yoichi

PY - 2005

Y1 - 2005

N2 - Chiral distortion of the basal four pyridyl nitrogen donors of the titled complex [Mo2(O)2(μ-S)2{μ-N,N,N′, N′-tetrakis(2-pyridylmethyl)-R-propylenediamine}]2+ has been found to be the reverse to that of the corresponding di-μ-oxo complex, on the basis of the inverse pattern of the circular dichroism spectra. Asymmetric distortion of the dimolybdenum(III) dimer [Mo2(μ-OH) 2(μ-CH3COO){μ-N,N,N′,N′-tetrakis(2- pyridylmethyl)ethylenediamine}]3+ has also been discussed.

AB - Chiral distortion of the basal four pyridyl nitrogen donors of the titled complex [Mo2(O)2(μ-S)2{μ-N,N,N′, N′-tetrakis(2-pyridylmethyl)-R-propylenediamine}]2+ has been found to be the reverse to that of the corresponding di-μ-oxo complex, on the basis of the inverse pattern of the circular dichroism spectra. Asymmetric distortion of the dimolybdenum(III) dimer [Mo2(μ-OH) 2(μ-CH3COO){μ-N,N,N′,N′-tetrakis(2- pyridylmethyl)ethylenediamine}]3+ has also been discussed.

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U2 - 10.1246/bcsj.78.2161

DO - 10.1246/bcsj.78.2161

M3 - 学術論文

AN - SCOPUS:33750615583

SN - 0009-2673

VL - 78

SP - 2161

EP - 2163

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 12

ER -