Catalytic asymmetric synthesis of descurainin via 1, 3-dipolar cycloaddition of a carbonyl ylide using Rh₂(R-TCPTTL)₄

Keyphrases

• 1,3-dipolar Cycloaddition 100%
• Carbonyl Ylide 100%
• Catalytic Asymmetric Synthesis 100%
• Tert-butyl 33%
• Regioselectivity 33%
• Demethylation 33%
• Stereoselectivity 33%
• Alkenes 33%
• Tetrakis 33%
• Tert 33%
• Enantioselectivity 33%
• Dirhodium Complex 33%
• Diazo 33%
• Formyl 33%
• 6,8-Dioxabicyclo[3.2.1]octanes 33%
• Fremy's Salt 33%
• NbCl5 33%

Chemistry

• 1,3-cycloaddition 100%
• Carbonyl Ylide 100%
• Asymmetric Synthesis 100%
• Alkene 33%
• Leucinate 33%
• Octane 33%
• Demethylation 33%
• Table Salt 33%