Bismuth(III)-Catalyzed Oxidative Cross-Coupling of 3-Hydroxycarbazoles with Arenols under an Oxygen Atmosphere

Kengo Kasama; Yuta Koike; Haoyang Dai; Takayuki Yakura

doi:10.1021/acs.orglett.3c02211

Bismuth(III)-Catalyzed Oxidative Cross-Coupling of 3-Hydroxycarbazoles with Arenols under an Oxygen Atmosphere

Kengo Kasama^*, Yuta Koike, Haoyang Dai, Takayuki Yakura^*

^*この論文の責任著者

分子合成化学研究室

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

抄録

A Bi(OTf)₃-catalyzed oxidative cross-coupling reaction of 3-hydroxycarbazoles with arenols was developed under mild conditions. Both substrates were used in a 1:1 molar ratio in the presence of a catalytic amount of Bi(OTf)₃. The reaction was carried out under an oxygen atmosphere at 30 °C to afford C₁-symmetric hydroxybiaryls in good yields (up to 94%) with high chemo- and regioselectivity.

本文言語	英語
ページ（範囲）	6501-6505
ページ数	5
ジャーナル	Organic Letters
巻	25
号	35
DOI	https://doi.org/10.1021/acs.orglett.3c02211
出版ステータス	出版済み - 2023/09/08

ASJC Scopus 主題領域

生化学
物理化学および理論化学
有機化学

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10.1021/acs.orglett.3c02211

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abstract = "A Bi(OTf)3-catalyzed oxidative cross-coupling reaction of 3-hydroxycarbazoles with arenols was developed under mild conditions. Both substrates were used in a 1:1 molar ratio in the presence of a catalytic amount of Bi(OTf)3. The reaction was carried out under an oxygen atmosphere at 30 °C to afford C1-symmetric hydroxybiaryls in good yields (up to 94%) with high chemo- and regioselectivity.",

author = "Kengo Kasama and Yuta Koike and Haoyang Dai and Takayuki Yakura",

note = "Publisher Copyright: {\textcopyright} 2023 American Chemical Society.",

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T1 - Bismuth(III)-Catalyzed Oxidative Cross-Coupling of 3-Hydroxycarbazoles with Arenols under an Oxygen Atmosphere

AU - Kasama, Kengo

AU - Koike, Yuta

AU - Dai, Haoyang

AU - Yakura, Takayuki

PY - 2023/9/8

Y1 - 2023/9/8

N2 - A Bi(OTf)3-catalyzed oxidative cross-coupling reaction of 3-hydroxycarbazoles with arenols was developed under mild conditions. Both substrates were used in a 1:1 molar ratio in the presence of a catalytic amount of Bi(OTf)3. The reaction was carried out under an oxygen atmosphere at 30 °C to afford C1-symmetric hydroxybiaryls in good yields (up to 94%) with high chemo- and regioselectivity.

AB - A Bi(OTf)3-catalyzed oxidative cross-coupling reaction of 3-hydroxycarbazoles with arenols was developed under mild conditions. Both substrates were used in a 1:1 molar ratio in the presence of a catalytic amount of Bi(OTf)3. The reaction was carried out under an oxygen atmosphere at 30 °C to afford C1-symmetric hydroxybiaryls in good yields (up to 94%) with high chemo- and regioselectivity.

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U2 - 10.1021/acs.orglett.3c02211

DO - 10.1021/acs.orglett.3c02211

M3 - 学術論文

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AN - SCOPUS:85170295240

SN - 1523-7060

VL - 25

SP - 6501

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JO - Organic Letters

JF - Organic Letters

IS - 35

ER -

Bismuth(III)-Catalyzed Oxidative Cross-Coupling of 3-Hydroxycarbazoles with Arenols under an Oxygen Atmosphere

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