抄録
New allosteric thymine receptors, 2,6-diamidopyridine derivatives tethered to an anthracene ring by a polyoxyethylene chain, were synthesized. In these receptors, binding of 1-butylthymine was enhanced by a factor of 4–6 by recognition of sodium cations, and the changes in the electron density of the anthracene ring were found to have influence on the allosterism by through-space interaction. The anthracene-linked diamidopyridines represent a rationally designed new class of artificial allosteric receptors.
| 本文言語 | 英語 |
|---|---|
| ページ（範囲） | 8091-8095 |
| ページ数 | 5 |
| ジャーナル | Journal of the American Chemical Society |
| 巻 | 115 |
| 号 | 18 |
| DOI | |
| 出版ステータス | 出版済み - 1993/09/01 |
ASJC Scopus 主題領域
- 触媒
- 化学一般
- 生化学
- コロイド化学および表面化学