@article{5024fce39fbc401f9f9b58cbc982868f,
title = "Application of a stereoselective rhodium(II)-catalyzed oxonium ylide formation-[2,3]-sigmatropic rearrangement of an α-diazo-β-keto ester to the synthesis of 2-epi-cinatrin C1 dimethyl ester",
abstract = "The Rh2(OAc)4-catalyzed oxonium ylide formation-[2,3]-sigmatropic rearrangement of a highly functionalized α-diazo-β-keto ester derived from d-glucose proceeded stereoselectively to give the corresponding tetrahydrofuran-3-one as a single diastereomer in high yield. This reaction was applied to the synthesis of 2-epi-cinatrin C1 dimethyl ester as a key step.",
keywords = "[2,3]-sigmatropic rearrangement, cinatrin, diazoketo ester, oxonium ylide, rhodium(II) catalyst",
author = "Takayuki Yakura and Ayaka Ozono and Katsuaki Matsui and Masayuki Yamashita and Tomoya Fujiwara",
year = "2013",
doi = "10.1055/s-0032-1317694",
language = "英語",
volume = "24",
pages = "65--68",
journal = "Synlett",
issn = "0936-5214",
publisher = "Georg Thieme Verlag",
number = "1",
}