Analysis of a tritium enhanced water spectrum between 7200 and 7245 cm -1 using new variational calculations

Michael J. Down, Jonathan Tennyson*, Masanori Hara, Yuji Hatano, Kaori Kobayashi

*この論文の責任著者

研究成果: ジャーナルへの寄稿学術論文査読

13 被引用数 (Scopus)

抄録

A tritium enhanced water absorption spectrum previously recorded in the 7200-7245 cm-1 region is analysed. Variational calculations for HTO predict absorption to be dominated by the 2ν3 vibrational band in this region. New assignment are made for HTO based on this line list with a band origin measured to be at 7236.03 cm-1. A calculated T2O line list predicts absorption in this region to be below the experimental detection limit despite the large quantity of tritium present. From 170 lines observed 37 known H216O lines are identified and 111 new HTO assignments are made.

本文言語英語
ページ(範囲)35-40
ページ数6
ジャーナルJournal of Molecular Spectroscopy
289
DOI
出版ステータス出版済み - 2013

ASJC Scopus 主題領域

  • 原子分子物理学および光学
  • 分光学
  • 物理化学および理論化学

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