抄録
Macrocyclic compounds consisting of three 2,6-pyridylene and three 3,5-pyridylene units linked by acetylene bonds were synthesized by a Sonogashira reaction. The X-ray structures showed π-stacked pairs of two macrocycles, in which a 2,6-pyridylene unit of the one molecule overlaps a 3,5-pyridylene of the other molecule because of dipole-dipole interaction. Atomic force microscope (AFM) measurements revealed fibril structures indicating the stacking of the rigid planar macrocycles. Hydrogen-bonding ability of the macrocyclic inside was demonstrated by the addition of octyl β-d-glucopyranoside.
本文言語 | 英語 |
---|---|
ページ(範囲) | 828-831 |
ページ数 | 4 |
ジャーナル | Organic Letters |
巻 | 16 |
号 | 3 |
DOI | |
出版ステータス | 出版済み - 2014/02/07 |
ASJC Scopus 主題領域
- 生化学
- 物理化学および理論化学
- 有機化学