A solid phase extraction using a chelate resin immobilizing carboxymethylated pentaethylenehexamine for separation and preconcentration of trace elements in water samples

Shigehiro Kagaya*, Emiko Maeba, Yoshinori Inoue, Waka Kamichatani, Takehiro Kajiwara, Hideyuki Yanai, Mitsuru Saito, Koji Tohda

*この論文の責任著者

研究成果: ジャーナルへの寄稿学術論文査読

93 被引用数 (Scopus)

抄録

A chelate resin immobilizing carboxymethylated pentaethylenehexamine (CM-PEHA resin) was prepared, and the potential for the separation and preconcentration of trace elements in water samples was evaluated through the adsorption/elution test for 62 elements. The CM-PEHA resin could quantitatively recover various elements, including Ag, Cd, Co, Cu, Fe, Ni, Pb, Ti, U, and Zn, and rare earth elements over a wide pH range, and also Mn at pH above 5 and V and Mo at pH below 7. This resin could also effectively remove major elements, such as alkali and alkaline earth elements, under acidic and neutral conditions. Solid phase extraction using the CM-PEHA resin was applicable to the determination of 10 trace elements, Cd, Co, Cu, Fe, Mn, Mo, Ni, Pb, V, and Zn, in certified reference materials (EnviroMAT EU-L-1 wastewater and ES-L-1 ground water) and treated wastewater and all elements except for Mn in surface seawater using inductively coupled plasma atomic emission spectrometry. The detection limits, defined as 3 times the standard deviation for the procedural blank using 500 mL of purified water (50-fold preconcentration, n = 8), ranged from 0.003 μg L-1 (Mn) to 0.28 μg L-1 (Zn) as the concentration in 500 mL of solution.

本文言語英語
ページ(範囲)146-152
ページ数7
ジャーナルTalanta
79
2
DOI
出版ステータス出版済み - 2009/07/15

ASJC Scopus 主題領域

  • 分析化学

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