TY - JOUR
T1 - A s-bridged CoIIICuIICoIII trinuclear complex with an unusual Copper(II) ion bound by four aliphatic thiolato donors
AU - Konno, Takumi
AU - Tamai, Toshihiro
AU - Kawamoto, Tatsuya
AU - Tsuge, Kiyoshi
AU - Igashira-Kamiyama, Asako
PY - 2009
Y1 - 2009
N2 - Treatment of ΔΔ-[NiII{CoIII(aet) 2(R,R-chxn)}2](ClO4)4 (Haet = 2-aminoethanethiol, R,R-chxn = 1R,2R-cyclohexanediamine) with Cu(ClO 4)2 in water gave ΔΔ-[CuII{Co III(aet)2(R,R-chxn)}2](ClO4) 4 (1), in which a central copper(II) ion is surrounded by four aliphatic thiolato donors in a twisted square-planar geometry. Complex 1 was converted to ΔΔ[CuICl{CoIII(aet) 2(R,R-chxn)}2](ClO4)2 (2) by treatment with NaCl in water, while 2 was reverted back to 1 by treatment with NaClO4.
AB - Treatment of ΔΔ-[NiII{CoIII(aet) 2(R,R-chxn)}2](ClO4)4 (Haet = 2-aminoethanethiol, R,R-chxn = 1R,2R-cyclohexanediamine) with Cu(ClO 4)2 in water gave ΔΔ-[CuII{Co III(aet)2(R,R-chxn)}2](ClO4) 4 (1), in which a central copper(II) ion is surrounded by four aliphatic thiolato donors in a twisted square-planar geometry. Complex 1 was converted to ΔΔ[CuICl{CoIII(aet) 2(R,R-chxn)}2](ClO4)2 (2) by treatment with NaCl in water, while 2 was reverted back to 1 by treatment with NaClO4.
UR - http://www.scopus.com/inward/record.url?scp=75249090834&partnerID=8YFLogxK
U2 - 10.1246/cl.2009.1074
DO - 10.1246/cl.2009.1074
M3 - 学術論文
AN - SCOPUS:75249090834
SN - 0366-7022
VL - 38
SP - 1074
EP - 1075
JO - Chemistry Letters
JF - Chemistry Letters
IS - 11
ER -