TY - JOUR
T1 - A novel nanocomposite material prepared by intercalating photoresponsive dendrimers into a layered double hydroxide
AU - Tanaka, Toshiyuki
AU - Nishimoto, Shunsuke
AU - Kameshima, Yoshikazu
AU - Matsukawa, Junpei
AU - Fujita, Yasuhiko
AU - Takaguchi, Yutaka
AU - Matsuda, Motohide
AU - Miyake, Michihiro
PY - 2010/2
Y1 - 2010/2
N2 - A novel combination for an inorganic-organic nanocomposite material was demonstrated. Anthryl dendron, i.e., poly(amidoamine) dendron with an anthracene chromophore group at the focal point, was incorporated in the interlayer space of ZnAl-NO3 type layered double hydroxide (LDH) through an anion-exchange reaction. The photoabsorption and fluorescence properties of the resulting material were different from those of the bare anthryl dendron molecule. It was suggested that the change in photochemical properties was due to the organization and π-π interaction of anthracene chromophores within the interlayer of the LDH.
AB - A novel combination for an inorganic-organic nanocomposite material was demonstrated. Anthryl dendron, i.e., poly(amidoamine) dendron with an anthracene chromophore group at the focal point, was incorporated in the interlayer space of ZnAl-NO3 type layered double hydroxide (LDH) through an anion-exchange reaction. The photoabsorption and fluorescence properties of the resulting material were different from those of the bare anthryl dendron molecule. It was suggested that the change in photochemical properties was due to the organization and π-π interaction of anthracene chromophores within the interlayer of the LDH.
KW - Dendrimer
KW - Layered double hydroxide
KW - Nanocomposites
KW - Photochemical properties
UR - http://www.scopus.com/inward/record.url?scp=75149139363&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2009.12.016
DO - 10.1016/j.jssc.2009.12.016
M3 - 学術論文
AN - SCOPUS:75149139363
SN - 0022-4596
VL - 183
SP - 479
EP - 484
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
IS - 2
ER -