A bis-bipyridine osmium(ii) complex with an N,S-chelating 2-aminoethanesulfinate: Photoinduced conversion of an amine to an imine donor group by air oxidation

Motoshi Tamura; Kiyoshi Tsuge; Asako Igashira-Kamiyama; Takumi Konno

doi:10.1039/c1cc14342e

A bis-bipyridine osmium(ii) complex with an N,S-chelating 2-aminoethanesulfinate: Photoinduced conversion of an amine to an imine donor group by air oxidation

Motoshi Tamura, Kiyoshi Tsuge, Asako Igashira-Kamiyama, Takumi Konno^*

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

17 被引用数 (Scopus)

抄録

Treatment of [Os(bpy)₂Cl₂] (bpy = 2,2′-bipyridine) with 2-aminoethanethiolate was accompanied by air oxidation to give [Os(2-aminoethanesulfinato-N,S)(bpy)₂]⁺ ([1]⁺), which was further oxidized by air to be converted into [Os(2-iminoethanesulfinato-N,S)(bpy)₂]⁺ ([2]⁺) under photoirradiation. Complex [2]⁺ was reverted back to [1] ⁺ by treatment with BH₄^-.

本文言語	英語
ページ（範囲）	12464-12466
ページ数	3
ジャーナル	Chemical Communications
巻	47
号	46
DOI	https://doi.org/10.1039/c1cc14342e
出版ステータス	出版済み - 2011/12/14

ASJC Scopus 主題領域

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学一般
表面、皮膜および薄膜
金属および合金
材料化学

文献へのアクセス

10.1039/c1cc14342e

フィンガープリント

「A bis-bipyridine osmium(ii) complex with an N,S-chelating 2-aminoethanesulfinate: Photoinduced conversion of an amine to an imine donor group by air oxidation」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{67f56afee59e4fa6ba1c12e9f4f668ee,

title = "A bis-bipyridine osmium(ii) complex with an N,S-chelating 2-aminoethanesulfinate: Photoinduced conversion of an amine to an imine donor group by air oxidation",

abstract = "Treatment of [Os(bpy)2Cl2] (bpy = 2,2′-bipyridine) with 2-aminoethanethiolate was accompanied by air oxidation to give [Os(2-aminoethanesulfinato-N,S)(bpy)2]+ ([1]+), which was further oxidized by air to be converted into [Os(2-iminoethanesulfinato-N,S)(bpy)2]+ ([2]+) under photoirradiation. Complex [2]+ was reverted back to [1] + by treatment with BH4-.",

author = "Motoshi Tamura and Kiyoshi Tsuge and Asako Igashira-Kamiyama and Takumi Konno",

year = "2011",

month = dec,

day = "14",

doi = "10.1039/c1cc14342e",

language = "英語",

volume = "47",

pages = "12464--12466",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "46",

}

A bis-bipyridine osmium(ii) complex with an N,S-chelating 2-aminoethanesulfinate: Photoinduced conversion of an amine to an imine donor group by air oxidation. / Tamura, Motoshi; Tsuge, Kiyoshi; Igashira-Kamiyama, Asako その他.
In: Chemical Communications, Vol. 47, No. 46, 14.12.2011, p. 12464-12466.

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

TY - JOUR

T1 - A bis-bipyridine osmium(ii) complex with an N,S-chelating 2-aminoethanesulfinate

T2 - Photoinduced conversion of an amine to an imine donor group by air oxidation

AU - Tamura, Motoshi

AU - Tsuge, Kiyoshi

AU - Igashira-Kamiyama, Asako

AU - Konno, Takumi

PY - 2011/12/14

Y1 - 2011/12/14

N2 - Treatment of [Os(bpy)2Cl2] (bpy = 2,2′-bipyridine) with 2-aminoethanethiolate was accompanied by air oxidation to give [Os(2-aminoethanesulfinato-N,S)(bpy)2]+ ([1]+), which was further oxidized by air to be converted into [Os(2-iminoethanesulfinato-N,S)(bpy)2]+ ([2]+) under photoirradiation. Complex [2]+ was reverted back to [1] + by treatment with BH4-.

AB - Treatment of [Os(bpy)2Cl2] (bpy = 2,2′-bipyridine) with 2-aminoethanethiolate was accompanied by air oxidation to give [Os(2-aminoethanesulfinato-N,S)(bpy)2]+ ([1]+), which was further oxidized by air to be converted into [Os(2-iminoethanesulfinato-N,S)(bpy)2]+ ([2]+) under photoirradiation. Complex [2]+ was reverted back to [1] + by treatment with BH4-.

UR - http://www.scopus.com/inward/record.url?scp=81255197392&partnerID=8YFLogxK

U2 - 10.1039/c1cc14342e

DO - 10.1039/c1cc14342e

M3 - 学術論文

AN - SCOPUS:81255197392

SN - 1359-7345

VL - 47

SP - 12464

EP - 12466

JO - Chemical Communications

JF - Chemical Communications

IS - 46

ER -