η3-coordination of hexadentate N,N,N′,N′ -tetrakis(2-pyridylmethyl)ethylenediamine (tpen) to a mononuclear fac-Re VIIO3 center. The isolation of a new class of metal-containing ligands

Ayako Mitani; Masaaki Abe; Kiyoshi Tsuge; Yoichi Sasaki

doi:10.1246/cl.2003.502

η³-coordination of hexadentate N,N,N′,N′ -tetrakis(2-pyridylmethyl)ethylenediamine (tpen) to a mononuclear fac-Re ^VIIO₃ center. The isolation of a new class of metal-containing ligands

Ayako Mitani, Masaaki Abe^*, Kiyoshi Tsuge, Yoichi Sasaki

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

6 被引用数 (Scopus)

抄録

Reaction of Re^VOCl₃(PPh₃)₂ with an equimolar amount of tpen affords fac-[Re^VIIO₃ (η³-tpenH)](ClO₄)₂ (1), in which the tpen ligand coordinates to the fac-Re^VIIO₃ center in a η³-mode, and the dangling bis(2-pyridylmethyl)amine arm in 1 is subsequently used to produce a heterobimetallic complex fac-,fac-[Re ^VIIO₃ (μ-η³:η ³-tpen)Re¹ (CO)₃](ClO₄)₂.

本文言語	英語
ページ（範囲）	502-503
ページ数	2
ジャーナル	Chemistry Letters
巻	32
号	6
DOI	https://doi.org/10.1246/cl.2003.502
出版ステータス	出版済み - 2003/06/05

ASJC Scopus 主題領域

化学一般

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10.1246/cl.2003.502

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引用スタイル

@article{720395d926a84adfa1d5d5b725562839,

title = "η3-coordination of hexadentate N,N,N′,N′ -tetrakis(2-pyridylmethyl)ethylenediamine (tpen) to a mononuclear fac-Re VIIO3 center. The isolation of a new class of metal-containing ligands",

abstract = "Reaction of ReVOCl3(PPh3)2 with an equimolar amount of tpen affords fac-[ReVIIO3 (η3-tpenH)](ClO4)2 (1), in which the tpen ligand coordinates to the fac-ReVIIO3 center in a η3-mode, and the dangling bis(2-pyridylmethyl)amine arm in 1 is subsequently used to produce a heterobimetallic complex fac-,fac-[Re VIIO3 (μ-η3:η 3-tpen)Re1 (CO)3](ClO4)2.",

author = "Ayako Mitani and Masaaki Abe and Kiyoshi Tsuge and Yoichi Sasaki",

year = "2003",

month = jun,

day = "5",

doi = "10.1246/cl.2003.502",

language = "英語",

volume = "32",

pages = "502--503",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "6",

}

η³-coordination of hexadentate N,N,N′,N′ -tetrakis(2-pyridylmethyl)ethylenediamine (tpen) to a mononuclear fac-Re ^VIIO₃ center. The isolation of a new class of metal-containing ligands. / Mitani, Ayako; Abe, Masaaki; Tsuge, Kiyoshi その他.
In: Chemistry Letters, Vol. 32, No. 6, 05.06.2003, p. 502-503.

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

TY - JOUR

T1 - η3-coordination of hexadentate N,N,N′,N′ -tetrakis(2-pyridylmethyl)ethylenediamine (tpen) to a mononuclear fac-Re VIIO3 center. The isolation of a new class of metal-containing ligands

AU - Mitani, Ayako

AU - Abe, Masaaki

AU - Tsuge, Kiyoshi

AU - Sasaki, Yoichi

PY - 2003/6/5

Y1 - 2003/6/5

N2 - Reaction of ReVOCl3(PPh3)2 with an equimolar amount of tpen affords fac-[ReVIIO3 (η3-tpenH)](ClO4)2 (1), in which the tpen ligand coordinates to the fac-ReVIIO3 center in a η3-mode, and the dangling bis(2-pyridylmethyl)amine arm in 1 is subsequently used to produce a heterobimetallic complex fac-,fac-[Re VIIO3 (μ-η3:η 3-tpen)Re1 (CO)3](ClO4)2.

AB - Reaction of ReVOCl3(PPh3)2 with an equimolar amount of tpen affords fac-[ReVIIO3 (η3-tpenH)](ClO4)2 (1), in which the tpen ligand coordinates to the fac-ReVIIO3 center in a η3-mode, and the dangling bis(2-pyridylmethyl)amine arm in 1 is subsequently used to produce a heterobimetallic complex fac-,fac-[Re VIIO3 (μ-η3:η 3-tpen)Re1 (CO)3](ClO4)2.

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U2 - 10.1246/cl.2003.502

DO - 10.1246/cl.2003.502

M3 - 学術論文

AN - SCOPUS:0042762337

SN - 0366-7022

VL - 32

SP - 502

EP - 503

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -