Tricopper(I) complexes encapsulating a {Cu3X3} core structure (X = Cl, Br, and I) in a polyaza cryptand

Kojiro Nagata; Tsubasa Hatanaka; Kensuke Fukui; Tomohiko Inomata; Tomohiro Ozawa; Kiyoshi Tsuge; Hideki Masuda; Yasuhiro Funahashi

doi:10.1246/cl.160105

Tricopper(I) complexes encapsulating a {Cu₃X₃} core structure (X = Cl, Br, and I) in a polyaza cryptand

Kojiro Nagata, Tsubasa Hatanaka, Kensuke Fukui, Tomohiko Inomata, Tomohiro Ozawa, Kiyoshi Tsuge^*, Hideki Masuda, Yasuhiro Funahashi

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

We report the synthesis and luminescent properties of halide-bridged tricopper(I) complexes with a polyaza cryptand having three 2,6-bis(aminomethyl)pyridyl spacers. The asymmetric {Cu₃X₃} structure was formed in the ligand shell, and emitted in both of the solid and solution states. DFT calculation and 1HNMR spectroscopic studies were performed on these luminescent cage-type compounds.

Original language	English
Pages (from-to)	541-543
Number of pages	3
Journal	Chemistry Letters
Volume	45
Issue number	5
DOIs	https://doi.org/10.1246/cl.160105
State	Published - 2016

Keywords

Luminescence
Polyaza cryptand
Tricopper(I) complex

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1246/cl.160105

Cite this

@article{bcbb4d3c19894986b59ea5b3c6d053c3,

title = "Tricopper(I) complexes encapsulating a {Cu3X3} core structure (X = Cl, Br, and I) in a polyaza cryptand",

abstract = "We report the synthesis and luminescent properties of halide-bridged tricopper(I) complexes with a polyaza cryptand having three 2,6-bis(aminomethyl)pyridyl spacers. The asymmetric {Cu3X3} structure was formed in the ligand shell, and emitted in both of the solid and solution states. DFT calculation and 1HNMR spectroscopic studies were performed on these luminescent cage-type compounds.",

keywords = "Luminescence, Polyaza cryptand, Tricopper(I) complex",

author = "Kojiro Nagata and Tsubasa Hatanaka and Kensuke Fukui and Tomohiko Inomata and Tomohiro Ozawa and Kiyoshi Tsuge and Hideki Masuda and Yasuhiro Funahashi",

note = "Funding Information: This work was supported by the PRESTO program from the Japan Science and Technology Agency to Y. Funahashi.",

year = "2016",

doi = "10.1246/cl.160105",

language = "英語",

volume = "45",

pages = "541--543",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "5",

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TY - JOUR

T1 - Tricopper(I) complexes encapsulating a {Cu3X3} core structure (X = Cl, Br, and I) in a polyaza cryptand

AU - Nagata, Kojiro

AU - Hatanaka, Tsubasa

AU - Fukui, Kensuke

AU - Inomata, Tomohiko

AU - Ozawa, Tomohiro

AU - Tsuge, Kiyoshi

AU - Masuda, Hideki

AU - Funahashi, Yasuhiro

N1 - Funding Information: This work was supported by the PRESTO program from the Japan Science and Technology Agency to Y. Funahashi.

PY - 2016

Y1 - 2016

N2 - We report the synthesis and luminescent properties of halide-bridged tricopper(I) complexes with a polyaza cryptand having three 2,6-bis(aminomethyl)pyridyl spacers. The asymmetric {Cu3X3} structure was formed in the ligand shell, and emitted in both of the solid and solution states. DFT calculation and 1HNMR spectroscopic studies were performed on these luminescent cage-type compounds.

AB - We report the synthesis and luminescent properties of halide-bridged tricopper(I) complexes with a polyaza cryptand having three 2,6-bis(aminomethyl)pyridyl spacers. The asymmetric {Cu3X3} structure was formed in the ligand shell, and emitted in both of the solid and solution states. DFT calculation and 1HNMR spectroscopic studies were performed on these luminescent cage-type compounds.

KW - Luminescence

KW - Polyaza cryptand

KW - Tricopper(I) complex

UR - http://www.scopus.com/inward/record.url?scp=84966376800&partnerID=8YFLogxK

U2 - 10.1246/cl.160105

DO - 10.1246/cl.160105

M3 - 学術論文

AN - SCOPUS:84966376800

SN - 0366-7022

VL - 45

SP - 541

EP - 543

JO - Chemistry Letters

JF - Chemistry Letters

IS - 5

ER -