@article{3a60ad4fb1c749b091629e297dc7a1ac,
title = "The unprecedented role of a CuII cryptand in the luminescence properties of a EuIII cryptate complex",
abstract = "A EuIII cryptate complex constructed from a CuII cryptand with an L tBu ligand, [EuIIICu 2 II (L tBu)2(NO3)3(MeOH)], and the corresponding CaII and NaI cryptates, [Ca IICu 2 II (L tBu) 2(NO3)2(MeOH)2] and [Na ICu 2 II (L tBu)2(Me 2CO)](BPh4), have been synthesized and characterized in order to shed light on the essential role of CuII in the luminescence of a EuIII cryptate. The unprecedented role of a CuII cryptand makes it possible to produce lanthanide luminescence in a Eu III cryptate complex and is successfully elucidated by comparison with the corresponding CaII and NaI cryptates.",
keywords = "Fluorescence spectroscopy, Lanthanoids, Metal complexes, UV/vis spectroscopy, X-ray structure determination",
author = "Hideki Ohtsu and Tomoya Suzuki and Hajime Ohtsuka and Ayumi Ishii and Miki Hasegawa",
note = "Funding Information: We are grateful to Dr. Franz Werner, Aoyama Gakuin University, and Prof. Dr. Masahiro Yamashita, Tohoku University, for their kind discussions. This work was supported by Grant-in-Aids for Young Scientists Start-up (No. 19850021, H.O.), Young Scientists A (No. 20685011, M.H.), and Scientific Research on Priority Areas (Chemistry of Coordination Space) to M.H. from the Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT), a grant from the Aoyama Gakuin 21st Century COE Program (New Functional Materials for Highly Efficient Energy System), and a High-Tech Research Center project for private universities with a matching fund subsidy from MEXT.",
year = "2009",
month = jul,
doi = "10.1007/s00706-009-0135-5",
language = "英語",
volume = "140",
pages = "783--787",
journal = "Monatshefte fur Chemie",
issn = "0026-9247",
publisher = "Springer-Verlag Wien",
number = "7",
}