The synthesis and spectral investigation of a novel highly water-soluble, aggregation-free antimony(V)-phthalocyanine absorbing light in optical therapeutical window

Hiroaki Isago; Harumi Fujita; Tamotsu Sugimori

doi:10.1016/j.jinorgbio.2012.08.004

The synthesis and spectral investigation of a novel highly water-soluble, aggregation-free antimony(V)-phthalocyanine absorbing light in optical therapeutical window

Hiroaki Isago^*, Harumi Fujita, Tamotsu Sugimori

^*Corresponding author for this work

Faculty of Liberal Arts and Sciences

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A novel antimony-phthalocyanine, [Sb(H₃tsppc)(OH)₂], where H₃tsppc denotes monodeprotonated tetrakis{(2′,6′- dimethyl-4′-sulfonic acid)phenoxyl}phthalocyaninate, has been synthesized through sulfonation of [Sb(tppc)(OH)₂]⁺ (tppc denotes tetrakis{(2′,6′-dimethyl)phenoxyl}phthalocyaninate) in concentrated sulfuric acid. This compound is highly soluble in water (ca. 4 × 10 ^{- 2} M) without surfactant or alcohol. Moreover, it has been found free from aggregation in water up to almost 10^{- 4} M, unlike its copper and metal-free analogues, and show an intense optical absorption and emission band in optical therapeutical window (700-800 nm). The axial hydroxyl groups play a crucial role in disaggregation of the antimony derivative in water.

Original language	English
Pages (from-to)	111-117
Number of pages	7
Journal	Journal of Inorganic Biochemistry
Volume	117
DOIs	https://doi.org/10.1016/j.jinorgbio.2012.08.004
State	Published - 2012/12

Keywords

Aggregation-free
Antimony complex
Phthalocyanine
Water-solubility

ASJC Scopus subject areas

Biochemistry
Inorganic Chemistry

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10.1016/j.jinorgbio.2012.08.004

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@article{340eb535063a42498002ca6311ca1d65,

title = "The synthesis and spectral investigation of a novel highly water-soluble, aggregation-free antimony(V)-phthalocyanine absorbing light in optical therapeutical window",

abstract = "A novel antimony-phthalocyanine, [Sb(H3tsppc)(OH)2], where H3tsppc denotes monodeprotonated tetrakis{(2′,6′- dimethyl-4′-sulfonic acid)phenoxyl}phthalocyaninate, has been synthesized through sulfonation of [Sb(tppc)(OH)2]+ (tppc denotes tetrakis{(2′,6′-dimethyl)phenoxyl}phthalocyaninate) in concentrated sulfuric acid. This compound is highly soluble in water (ca. 4 × 10 - 2 M) without surfactant or alcohol. Moreover, it has been found free from aggregation in water up to almost 10- 4 M, unlike its copper and metal-free analogues, and show an intense optical absorption and emission band in optical therapeutical window (700-800 nm). The axial hydroxyl groups play a crucial role in disaggregation of the antimony derivative in water.",

keywords = "Aggregation-free, Antimony complex, Phthalocyanine, Water-solubility",

author = "Hiroaki Isago and Harumi Fujita and Tamotsu Sugimori",

note = "Funding Information: This work was supported in part by JSPS KAKENHI (No. 20550170 ). ",

year = "2012",

month = dec,

doi = "10.1016/j.jinorgbio.2012.08.004",

language = "英語",

volume = "117",

pages = "111--117",

journal = "Journal of Inorganic Biochemistry",

issn = "0162-0134",

publisher = "Elsevier Inc.",

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TY - JOUR

T1 - The synthesis and spectral investigation of a novel highly water-soluble, aggregation-free antimony(V)-phthalocyanine absorbing light in optical therapeutical window

AU - Isago, Hiroaki

AU - Fujita, Harumi

AU - Sugimori, Tamotsu

N1 - Funding Information: This work was supported in part by JSPS KAKENHI (No. 20550170 ).

PY - 2012/12

Y1 - 2012/12

N2 - A novel antimony-phthalocyanine, [Sb(H3tsppc)(OH)2], where H3tsppc denotes monodeprotonated tetrakis{(2′,6′- dimethyl-4′-sulfonic acid)phenoxyl}phthalocyaninate, has been synthesized through sulfonation of [Sb(tppc)(OH)2]+ (tppc denotes tetrakis{(2′,6′-dimethyl)phenoxyl}phthalocyaninate) in concentrated sulfuric acid. This compound is highly soluble in water (ca. 4 × 10 - 2 M) without surfactant or alcohol. Moreover, it has been found free from aggregation in water up to almost 10- 4 M, unlike its copper and metal-free analogues, and show an intense optical absorption and emission band in optical therapeutical window (700-800 nm). The axial hydroxyl groups play a crucial role in disaggregation of the antimony derivative in water.

AB - A novel antimony-phthalocyanine, [Sb(H3tsppc)(OH)2], where H3tsppc denotes monodeprotonated tetrakis{(2′,6′- dimethyl-4′-sulfonic acid)phenoxyl}phthalocyaninate, has been synthesized through sulfonation of [Sb(tppc)(OH)2]+ (tppc denotes tetrakis{(2′,6′-dimethyl)phenoxyl}phthalocyaninate) in concentrated sulfuric acid. This compound is highly soluble in water (ca. 4 × 10 - 2 M) without surfactant or alcohol. Moreover, it has been found free from aggregation in water up to almost 10- 4 M, unlike its copper and metal-free analogues, and show an intense optical absorption and emission band in optical therapeutical window (700-800 nm). The axial hydroxyl groups play a crucial role in disaggregation of the antimony derivative in water.

KW - Aggregation-free

KW - Antimony complex

KW - Phthalocyanine

KW - Water-solubility

UR - http://www.scopus.com/inward/record.url?scp=84867435027&partnerID=8YFLogxK

U2 - 10.1016/j.jinorgbio.2012.08.004

DO - 10.1016/j.jinorgbio.2012.08.004

M3 - 学術論文

C2 - 23085590

AN - SCOPUS:84867435027

SN - 0162-0134

VL - 117

SP - 111

EP - 117

JO - Journal of Inorganic Biochemistry

JF - Journal of Inorganic Biochemistry

ER -

The synthesis and spectral investigation of a novel highly water-soluble, aggregation-free antimony(V)-phthalocyanine absorbing light in optical therapeutical window

Abstract

Keywords

ASJC Scopus subject areas

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