The hollow on the excited-state potential for photo-induced 'Jahn-Teller' distortion of copper complexes revealed by ultrafast spectroscopy

Munetaka Iwamura*, Kunihiko Ishii, Satoshi Takeuchi, Tahei Tahara

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Ultrafast dynamics of photo-induced structural change of [Cu(dmphen) 2]+ was studied by femtosecond emission spectroscopy and 25-fs time-resolved pump-probe spectroscopy. It was found that the Si state remains undistorted for 660 fs before structural change, being trapped in a shallow potential minimum at the perpendicular configuration on the Si potential.

Original languageEnglish
Title of host publication2007 Conference on Lasers and Electro-Optics - Pacific Rim, CLEO/PACIFIC RIM
DOIs
StatePublished - 2007
Event2007 Conference on Lasers and Electro-Optics - Pacific Rim, CLEO/PACIFIC RIM - Seoul, Korea, Republic of
Duration: 2007/08/262007/08/31

Publication series

NamePacific Rim Conference on Lasers and Electro-Optics, CLEO - Technical Digest

Conference

Conference2007 Conference on Lasers and Electro-Optics - Pacific Rim, CLEO/PACIFIC RIM
Country/TerritoryKorea, Republic of
CitySeoul
Period2007/08/262007/08/31

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Electrical and Electronic Engineering

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