The formation and stereochemistry of [CoIII3(L-cys-N,S)n(aet)6-n]3-n Type S-Bridged Complexes (n=0-6, L-cys=L-cysteinate, and aet=2-aminoethanethiolate)

Takumi Konno*, Sen Ichi Aizawa, Jinsai Hidaka

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

Three kinds of S-bridged trinuclear complexes, ΔLLLΔLLL-[Co3(L-cys-N,S)6]3-, ΔLLLΔ- and ΔLLLΔ-[Co3(L-cys-N,S)3(aet)3]0, and [Co3(aet)6]3+1) were formed by the reaction of a mixture of ΔLLL-fac-[Co(L-cys-N,S)3]3- (L-cys=L-cysteinate) and fac-[Co(aet)3] (aet=2-aminoethane-thiolate) with [CoCl(NH3)5]2+. The reaction with an excess amount of Co2+ led to the formation of seven kinds of S-bridged complexes, [Co3(L-cys-N,S)n(aet)6-n]3-n(n=0-6).

Original languageEnglish
Pages (from-to)585-587
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume62
Issue number2
DOIs
StatePublished - 1989/02

ASJC Scopus subject areas

  • General Chemistry

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