Abstract
Three kinds of S-bridged trinuclear complexes, ΔLLLΔLLL-[Co3(L-cys-N,S)6]3-, ΔLLLΔ- and ΔLLLΔ-[Co3(L-cys-N,S)3(aet)3]0, and [Co3(aet)6]3+1) were formed by the reaction of a mixture of ΔLLL-fac-[Co(L-cys-N,S)3]3- (L-cys=L-cysteinate) and fac-[Co(aet)3] (aet=2-aminoethane-thiolate) with [CoCl(NH3)5]2+. The reaction with an excess amount of Co2+ led to the formation of seven kinds of S-bridged complexes, [Co3(L-cys-N,S)n(aet)6-n]3-n(n=0-6).
Original language | English |
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Pages (from-to) | 585-587 |
Number of pages | 3 |
Journal | Bulletin of the Chemical Society of Japan |
Volume | 62 |
Issue number | 2 |
DOIs | |
State | Published - 1989/02 |
ASJC Scopus subject areas
- General Chemistry