TY - JOUR
T1 - Synthetic hydrogen-bonding receptors for biologically essential monosaccharides
AU - Inouye, Masahiko
PY - 2000/11
Y1 - 2000/11
N2 - Novel macrocyclic saccharide receptors that possess terpyridine skeletons as a hydrogen-bonding site are presented. On modification of the hydrogen-bonding sites and the macrocyclic bridges, the receptors showed selective bindings for ribofuranosides, deoxyribofuranosides, and glucopyranosides, respectively. The binding affinities of the receptors were very high, so that native monosaccharides were solubilized into non-polar solvents in the presence of the receptors. The hydrogen-bonding interactions and the binding modes between them were characterized by 1H NMR spectroscopy.
AB - Novel macrocyclic saccharide receptors that possess terpyridine skeletons as a hydrogen-bonding site are presented. On modification of the hydrogen-bonding sites and the macrocyclic bridges, the receptors showed selective bindings for ribofuranosides, deoxyribofuranosides, and glucopyranosides, respectively. The binding affinities of the receptors were very high, so that native monosaccharides were solubilized into non-polar solvents in the presence of the receptors. The hydrogen-bonding interactions and the binding modes between them were characterized by 1H NMR spectroscopy.
UR - http://www.scopus.com/inward/record.url?scp=11144224667&partnerID=8YFLogxK
U2 - 10.5059/yukigoseikyokaishi.58.1077
DO - 10.5059/yukigoseikyokaishi.58.1077
M3 - 学術論文
AN - SCOPUS:11144224667
SN - 0037-9980
VL - 58
SP - 1077
EP - 1082
JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
IS - 11
ER -