Synthesis, X-ray structure, photophysical properties, and theoretical studies of six-membered cyclometalated iridium(III) complexes: Revisiting Ir(pnbi)₂(acac)

Keyphrases

• Photophysical Properties 100%
• X-ray Structure 100%
• Six-membered 100%
• Acac 100%
• Cyclometalated Iridium(III) Complex 100%
• Five-membered 75%
• Phenanthrene 50%
• DFT Calculations 50%
• Metallocycle 50%
• X-ray Diffraction (XRD) Analysis 25%
• Bulky Substituents 25%
• Quantum Yield 25%
• Repulsion 25%
• Phenyl 25%
• Benzimidazole 25%
• Total Energy 25%
• Red Emission 25%
• Ring Structure 25%
• Ir Complexes 25%
• Relative Stability 25%
• Six-membered Rings 25%
• 1H-benzimidazole 25%
• Acetylacetonate 25%
• Steric Bulk 25%
• N-complex 25%
• Polyaromatic Ring 25%
• N-ring 25%
• Naphthalene Moiety 25%
• Cyclometalation 25%

Chemistry

• Phenanthrenes 100%
• Iridium 100%
• Density Functional Theory 100%
• Quantum Yield 50%
• Single Crystal X-Ray Diffraction 50%
• X-Ray Diffraction 50%
• Red 50%
• Benzimidazole 50%
• Acetylacetonate 50%
• 1H-Benzimidazole 50%
• stability 50%
• Volume 50%
• Naphthalene 50%
• six membered rings 50%