Synthesis of d1-aspterric acid, a carotane type sesquiterpene

Takashi Harayama; Yutaka Shinkai; Yukiya Hashimoto; Hideto Fukushi; Yasuo Inubushi

doi:10.1016/S0040-4039(00)88407-5

Synthesis of d1-aspterric acid, a carotane type sesquiterpene

Takashi Harayama^*, Yutaka Shinkai, Yukiya Hashimoto, Hideto Fukushi, Yasuo Inubushi

^*Corresponding author for this work

Clinical Pharmacokinetics

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A carotane type sesquiterpene, aspterric acid (1) was stereoselectively synthesized through Robinson annulation of 2 with MVK, dimethylation of 15, introduction of cyano group to 19 and ring contraction of 25.

Original language	English
Pages (from-to)	5241-5244
Number of pages	4
Journal	Tetrahedron Letters
Volume	24
Issue number	47
DOIs	https://doi.org/10.1016/S0040-4039(00)88407-5
State	Published - 1983

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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@article{745190d127c5434aa31c0d3d7d553fc0,

title = "Synthesis of d1-aspterric acid, a carotane type sesquiterpene",

abstract = "A carotane type sesquiterpene, aspterric acid (1) was stereoselectively synthesized through Robinson annulation of 2 with MVK, dimethylation of 15, introduction of cyano group to 19 and ring contraction of 25.",

author = "Takashi Harayama and Yutaka Shinkai and Yukiya Hashimoto and Hideto Fukushi and Yasuo Inubushi",

year = "1983",

doi = "10.1016/S0040-4039(00)88407-5",

language = "英語",

volume = "24",

pages = "5241--5244",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd.",

number = "47",

}

TY - JOUR

T1 - Synthesis of d1-aspterric acid, a carotane type sesquiterpene

AU - Harayama, Takashi

AU - Shinkai, Yutaka

AU - Hashimoto, Yukiya

AU - Fukushi, Hideto

AU - Inubushi, Yasuo

PY - 1983

Y1 - 1983

N2 - A carotane type sesquiterpene, aspterric acid (1) was stereoselectively synthesized through Robinson annulation of 2 with MVK, dimethylation of 15, introduction of cyano group to 19 and ring contraction of 25.

AB - A carotane type sesquiterpene, aspterric acid (1) was stereoselectively synthesized through Robinson annulation of 2 with MVK, dimethylation of 15, introduction of cyano group to 19 and ring contraction of 25.

UR - http://www.scopus.com/inward/record.url?scp=0005685998&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)88407-5

DO - 10.1016/S0040-4039(00)88407-5

M3 - 学術論文

AN - SCOPUS:0005685998

SN - 0040-4039

VL - 24

SP - 5241

EP - 5244

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 47

ER -

Synthesis of d1-aspterric acid, a carotane type sesquiterpene

Abstract

ASJC Scopus subject areas

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