Synthesis of 6-trimethylsilyl-α-pyrone from 2, 6-bis (trimethylsilyl)-pyran via mild aerobic oxidation

Dejun Zhou; Matsuya Yuji

doi:10.6023/cjoc201209027

Synthesis of 6-trimethylsilyl-α-pyrone from 2, 6-bis (trimethylsilyl)-pyran via mild aerobic oxidation

Dejun Zhou^*, Matsuya Yuji

^*Corresponding author for this work

Synthetic and Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In this study, an effective and mild method for the synthesis of 6-trimethylsilyl-α-pyrone was successfully developed. 6-Trimethylsilyl-α-pyrone, a very important intermediate in organic synthesis, was mildly synthesized from pyrane derivative via an aerobic oxidation at room temperature, without any solvents and catalysts. Furthermore, the possible mechanism of the reaction was proposed.

Original language	English
Pages (from-to)	375-377
Number of pages	3
Journal	Chinese Journal of Organic Chemistry
Volume	33
Issue number	2
DOIs	https://doi.org/10.6023/cjoc201209027
State	Published - 2013/02

Keywords

6-trimethylsilyl-α-pyrone
Mechanism
Oxidation

ASJC Scopus subject areas

Organic Chemistry

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10.6023/cjoc201209027

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title = "Synthesis of 6-trimethylsilyl-α-pyrone from 2, 6-bis (trimethylsilyl)-pyran via mild aerobic oxidation",

abstract = "In this study, an effective and mild method for the synthesis of 6-trimethylsilyl-α-pyrone was successfully developed. 6-Trimethylsilyl-α-pyrone, a very important intermediate in organic synthesis, was mildly synthesized from pyrane derivative via an aerobic oxidation at room temperature, without any solvents and catalysts. Furthermore, the possible mechanism of the reaction was proposed.",

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author = "Dejun Zhou and Matsuya Yuji",

year = "2013",

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AU - Zhou, Dejun

AU - Yuji, Matsuya

PY - 2013/2

Y1 - 2013/2

N2 - In this study, an effective and mild method for the synthesis of 6-trimethylsilyl-α-pyrone was successfully developed. 6-Trimethylsilyl-α-pyrone, a very important intermediate in organic synthesis, was mildly synthesized from pyrane derivative via an aerobic oxidation at room temperature, without any solvents and catalysts. Furthermore, the possible mechanism of the reaction was proposed.

AB - In this study, an effective and mild method for the synthesis of 6-trimethylsilyl-α-pyrone was successfully developed. 6-Trimethylsilyl-α-pyrone, a very important intermediate in organic synthesis, was mildly synthesized from pyrane derivative via an aerobic oxidation at room temperature, without any solvents and catalysts. Furthermore, the possible mechanism of the reaction was proposed.

KW - 6-trimethylsilyl-α-pyrone

KW - Mechanism

KW - Oxidation

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U2 - 10.6023/cjoc201209027

DO - 10.6023/cjoc201209027

M3 - 学術論文

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JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 2

ER -

Synthesis of 6-trimethylsilyl-α-pyrone from 2, 6-bis (trimethylsilyl)-pyran via mild aerobic oxidation

Abstract

Keywords

ASJC Scopus subject areas

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