Synthesis of 1-Adamantylaminogermylene and Its Chalcogenation Reactions

Mariko Yukimoto; Kazuaki Kanda; Takamasa Aoki; Yoshiyuki Mizuhata; Norihiro Tokitoh

doi:10.1002/ejic.202300663

Synthesis of 1-Adamantylaminogermylene and Its Chalcogenation Reactions

Mariko Yukimoto^*, Kazuaki Kanda, Takamasa Aoki, Yoshiyuki Mizuhata, Norihiro Tokitoh^*

^*Corresponding author for this work

Materials Design and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis, isolation, and characterization of 1-adamantylaminogermylene 1 have been achieved utilizing kinetic stabilization with a bulky aryl group on the germanium atom. Aminogermylene 1 was found to be stable in toluene solution at 110 °C for 3 days without decomposition. The chalcogenation reaction of 1 aiming to synthesize heavy amides gave the head-to-tail type dimers of the corresponding heavy amides.

Original language	English
Article number	e202300663
Journal	European Journal of Inorganic Chemistry
Volume	27
Issue number	7
DOIs	https://doi.org/10.1002/ejic.202300663
State	Published - 2024/03/01

Keywords

Aminogermylene
Chalcogenation
Kinetic Stabilization

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/ejic.202300663

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title = "Synthesis of 1-Adamantylaminogermylene and Its Chalcogenation Reactions",

abstract = "The synthesis, isolation, and characterization of 1-adamantylaminogermylene 1 have been achieved utilizing kinetic stabilization with a bulky aryl group on the germanium atom. Aminogermylene 1 was found to be stable in toluene solution at 110 °C for 3 days without decomposition. The chalcogenation reaction of 1 aiming to synthesize heavy amides gave the head-to-tail type dimers of the corresponding heavy amides.",

keywords = "Aminogermylene, Chalcogenation, Kinetic Stabilization",

author = "Mariko Yukimoto and Kazuaki Kanda and Takamasa Aoki and Yoshiyuki Mizuhata and Norihiro Tokitoh",

note = "Publisher Copyright: {\textcopyright} 2023 Wiley-VCH GmbH.",

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doi = "10.1002/ejic.202300663",

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T1 - Synthesis of 1-Adamantylaminogermylene and Its Chalcogenation Reactions

AU - Yukimoto, Mariko

AU - Kanda, Kazuaki

AU - Aoki, Takamasa

AU - Mizuhata, Yoshiyuki

AU - Tokitoh, Norihiro

PY - 2024/3/1

Y1 - 2024/3/1

N2 - The synthesis, isolation, and characterization of 1-adamantylaminogermylene 1 have been achieved utilizing kinetic stabilization with a bulky aryl group on the germanium atom. Aminogermylene 1 was found to be stable in toluene solution at 110 °C for 3 days without decomposition. The chalcogenation reaction of 1 aiming to synthesize heavy amides gave the head-to-tail type dimers of the corresponding heavy amides.

AB - The synthesis, isolation, and characterization of 1-adamantylaminogermylene 1 have been achieved utilizing kinetic stabilization with a bulky aryl group on the germanium atom. Aminogermylene 1 was found to be stable in toluene solution at 110 °C for 3 days without decomposition. The chalcogenation reaction of 1 aiming to synthesize heavy amides gave the head-to-tail type dimers of the corresponding heavy amides.

KW - Aminogermylene

KW - Chalcogenation

KW - Kinetic Stabilization

UR - http://www.scopus.com/inward/record.url?scp=85182246246&partnerID=8YFLogxK

U2 - 10.1002/ejic.202300663

DO - 10.1002/ejic.202300663

M3 - 学術論文

AN - SCOPUS:85182246246

SN - 1434-1948

VL - 27

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 7

M1 - e202300663

ER -

Synthesis of 1-Adamantylaminogermylene and Its Chalcogenation Reactions

Abstract

Keywords

ASJC Scopus subject areas

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