TY - JOUR
T1 - Synthesis of α-Substituted Enoximes with Nucleophiles via Nitrosoallenes
AU - Tanimoto, Hiroki
AU - Yokoyama, Keiichi
AU - Mizutani, Yusuke
AU - Shitaoka, Takashi
AU - Morimoto, Tsumoru
AU - Nishiyama, Yasuhiro
AU - Kakiuchi, Kiyomi
N1 - Publisher Copyright:
© 2015 American Chemical Society.
PY - 2016/1/15
Y1 - 2016/1/15
N2 - This paper reports nitrosoallene-mediated synthesis of α-substituted enoximes. Nucleophilic substitution of nitrosoallenes, a novel chemical species prepared from allenyl N-hydroxysulfonamides, afforded α-functionalized enoximes. Introduction of various nucleophiles proceeded smoothly to form C-N, C-O, C-S, C-F, and C-C bonds in the presence of azodicarboxylates.
AB - This paper reports nitrosoallene-mediated synthesis of α-substituted enoximes. Nucleophilic substitution of nitrosoallenes, a novel chemical species prepared from allenyl N-hydroxysulfonamides, afforded α-functionalized enoximes. Introduction of various nucleophiles proceeded smoothly to form C-N, C-O, C-S, C-F, and C-C bonds in the presence of azodicarboxylates.
UR - http://www.scopus.com/inward/record.url?scp=84954447365&partnerID=8YFLogxK
U2 - 10.1021/acs.joc.5b02364
DO - 10.1021/acs.joc.5b02364
M3 - 学術論文
C2 - 26694102
AN - SCOPUS:84954447365
SN - 0022-3263
VL - 81
SP - 559
EP - 574
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 2
ER -