Sub-natural linewidth Auger electron spectroscopy of the 2s hole decay in H2S

Y. Hikosaka; P. Lablanquie; F. Penent; J. G. Lambourne; R. I. Hall; T. Aoto; K. Ito

doi:10.1016/j.elspec.2004.02.019

Sub-natural linewidth Auger electron spectroscopy of the 2s hole decay in H₂S

Y. Hikosaka^*, P. Lablanquie, F. Penent, J. G. Lambourne, R. I. Hall, T. Aoto, K. Ito

^*Corresponding author for this work

Faculty of Liberal Arts and Sciences

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Threshold photoelectron-Auger electron coincidence spectroscopy has been applied to the sulphur 2s region of H₂S, where the Auger electron spectrum is measured in coincidence with threshold electrons. Formation of H₂S⁺⁺[(S2p)^-1(V)^-1] states via the L₁L_2,3V Coster-Kronig transitions is observed above the S2s photoionization threshold. Even below threshold, formation of these H ₂S⁺⁺ states is seen and is due to direct double ionization. A sub-natural linewidth regime is achieved with this coincidence method and three structures resulting from overlaps of the H₂S ⁺⁺[(S2p)^-1(V)^-1] states appear in the spectra. The three structures probably correspond to H₂S⁺⁺ states with the 2b₁, 5a₁ and 2b₂ holes.

Original language	English
Pages (from-to)	287-291
Number of pages	5
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	137-140
Issue number	SPEC. ISS.
DOIs	https://doi.org/10.1016/j.elspec.2004.02.019
State	Published - 2004/07

Keywords

Auger transition
Coincidence spectroscopy
HS
Sub-natural linewidth
Sulfur 2s hole
Threshold electron

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Radiation
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry

Access to Document

10.1016/j.elspec.2004.02.019

Cite this

@article{fff472f8bbd041a59eb15d9d877c7e56,

title = "Sub-natural linewidth Auger electron spectroscopy of the 2s hole decay in H2S",

abstract = "Threshold photoelectron-Auger electron coincidence spectroscopy has been applied to the sulphur 2s region of H2S, where the Auger electron spectrum is measured in coincidence with threshold electrons. Formation of H2S++[(S2p)-1(V)-1] states via the L1L2,3V Coster-Kronig transitions is observed above the S2s photoionization threshold. Even below threshold, formation of these H 2S++ states is seen and is due to direct double ionization. A sub-natural linewidth regime is achieved with this coincidence method and three structures resulting from overlaps of the H2S ++[(S2p)-1(V)-1] states appear in the spectra. The three structures probably correspond to H2S++ states with the 2b1, 5a1 and 2b2 holes.",

keywords = "Auger transition, Coincidence spectroscopy, HS, Sub-natural linewidth, Sulfur 2s hole, Threshold electron",

author = "Y. Hikosaka and P. Lablanquie and F. Penent and Lambourne, {J. G.} and Hall, {R. I.} and T. Aoto and K. Ito",

note = "Funding Information: The authors thank Prof. N. Kosugi and Dr. J. Adachi for valuable discussion. The authors are grateful to the staff of the Photon Factory for the stable operation of the storage ring. PL, FP and JGL thank the JSPS and CNRS for financial support. RIH is grateful to the Ministry of Education, Culture, Sports, Science and Technology of Japan for his stay at the Photon Factory. This work has been performed under the approval of the Photon Factory Advisory Committee (01G202). ",

year = "2004",

month = jul,

doi = "10.1016/j.elspec.2004.02.019",

language = "英語",

volume = "137-140",

pages = "287--291",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier B.V.",

number = "SPEC. ISS.",

}

TY - JOUR

T1 - Sub-natural linewidth Auger electron spectroscopy of the 2s hole decay in H2S

AU - Hikosaka, Y.

AU - Lablanquie, P.

AU - Penent, F.

AU - Lambourne, J. G.

AU - Hall, R. I.

AU - Aoto, T.

AU - Ito, K.

N1 - Funding Information: The authors thank Prof. N. Kosugi and Dr. J. Adachi for valuable discussion. The authors are grateful to the staff of the Photon Factory for the stable operation of the storage ring. PL, FP and JGL thank the JSPS and CNRS for financial support. RIH is grateful to the Ministry of Education, Culture, Sports, Science and Technology of Japan for his stay at the Photon Factory. This work has been performed under the approval of the Photon Factory Advisory Committee (01G202).

PY - 2004/7

Y1 - 2004/7

N2 - Threshold photoelectron-Auger electron coincidence spectroscopy has been applied to the sulphur 2s region of H2S, where the Auger electron spectrum is measured in coincidence with threshold electrons. Formation of H2S++[(S2p)-1(V)-1] states via the L1L2,3V Coster-Kronig transitions is observed above the S2s photoionization threshold. Even below threshold, formation of these H 2S++ states is seen and is due to direct double ionization. A sub-natural linewidth regime is achieved with this coincidence method and three structures resulting from overlaps of the H2S ++[(S2p)-1(V)-1] states appear in the spectra. The three structures probably correspond to H2S++ states with the 2b1, 5a1 and 2b2 holes.

AB - Threshold photoelectron-Auger electron coincidence spectroscopy has been applied to the sulphur 2s region of H2S, where the Auger electron spectrum is measured in coincidence with threshold electrons. Formation of H2S++[(S2p)-1(V)-1] states via the L1L2,3V Coster-Kronig transitions is observed above the S2s photoionization threshold. Even below threshold, formation of these H 2S++ states is seen and is due to direct double ionization. A sub-natural linewidth regime is achieved with this coincidence method and three structures resulting from overlaps of the H2S ++[(S2p)-1(V)-1] states appear in the spectra. The three structures probably correspond to H2S++ states with the 2b1, 5a1 and 2b2 holes.

KW - Auger transition

KW - Coincidence spectroscopy

KW - HS

KW - Sub-natural linewidth

KW - Sulfur 2s hole

KW - Threshold electron

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U2 - 10.1016/j.elspec.2004.02.019

DO - 10.1016/j.elspec.2004.02.019

M3 - 学術論文

AN - SCOPUS:2942623840

SN - 0368-2048

VL - 137-140

SP - 287

EP - 291

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

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