@inproceedings{b2fd9b88a6574da893fbbfa54beca34c,
title = "Study on new method and mechanism of low-temperature methanol synthesis",
abstract = "The methanol could be synthesized from the CO/CO2/H2 on Cu/ZnO catalysts using alcohol solvent at 443 K and 3.0 Mpa. The activity of the catalyst with ZnO as carrier (Cu/ZnO) was the highest in all catalysts with Y2O3, La2O3, Al2O 3, or MgO as carrier separately, and the 2-butanol as solvent exhibited the highest activity in this reaction. The studying results of the reaction mechanism show that at first adsorbed formate species were formed by adsorbing the CO/CO2/H2 on Cu/ZnO catalyst, and then the 2-butyl formate was formed by the reaction of adsorbed formate species with 2-butanol, at last the 2-butyl formate is reduced by hydrogen atoms on Cu to form methanol. The 2-butanol used in this reaction not only significantly decreased the reaction temperature due to its promotional action, but also was not consumed due to its regeneration by hydrogenation of the 2-butyl formate, acting like a catalytic solvent.",
keywords = "2-Butanol, CO/CO/H, In-situ DRIFTS, Methanol",
author = "Wenze Li and Baoyan Zhang and Ruiqin Yang and Chengxue L{\"u} and Ling Zeng and Liujiu Xiao and Ying Xie and Peng Lu and Chuang Xing and Lei Shi and Noritatsu Tsubaki",
year = "2011",
doi = "10.1109/ICMREE.2011.5930597",
language = "英語",
isbn = "9781612847504",
series = "ICMREE2011 - Proceedings 2011 International Conference on Materials for Renewable Energy and Environment",
pages = "1404--1407",
booktitle = "ICMREE2011 - Proceedings 2011 International Conference on Materials for Renewable Energy and Environment",
note = "2011 International Conference on Materials for Renewable Energy and Environment, ICMREE2011 ; Conference date: 20-05-2011 Through 22-05-2011",
}