Abstract
The synthesis, characterization and physical properties of two isopropyl TTF semisquarates, TTFsqiPr and EDT-TTFsqiPr, are reported. These molecules show a solvatochromism effect in solution and electrical conductivity in the solid state in their neutral form. These behaviors can be explained in terms of a small electrical charge redistribution from the TTF-centered HOMO to the semisquarate-centered LUMO of the molecules.
| Original language | English |
|---|---|
| Pages (from-to) | 1249-1254 |
| Number of pages | 6 |
| Journal | New Journal of Chemistry |
| Volume | 33 |
| Issue number | 6 |
| DOIs | |
| State | Published - 2009 |
ASJC Scopus subject areas
- Catalysis
- General Chemistry
- Materials Chemistry