Structure and magnetic property of a macrocyclic tetranuclear copper(II) complex with phenoxo-and hydroxo-bridges and large and small Cu-O-Cu angles

Makoto Handa; Toshikazu Takemoto; Laurence K. Thompson; Masahiro Mikuriya; Nobuyuki Nagao; Shinichiro Ikemi; Jong Wan Lim; Tamotsu Sugimori; Ichiro Hiromitsu; Kuninobu Kasuga

doi:10.1246/cl.2001.316

Structure and magnetic property of a macrocyclic tetranuclear copper(II) complex with phenoxo-and hydroxo-bridges and large and small Cu-O-Cu angles

Makoto Handa^*, Toshikazu Takemoto, Laurence K. Thompson, Masahiro Mikuriya, Nobuyuki Nagao, Shinichiro Ikemi, Jong Wan Lim, Tamotsu Sugimori, Ichiro Hiromitsu, Kuninobu Kasuga

^*Corresponding author for this work

Faculty of Liberal Arts and Sciences

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Reaction of a macrocyclic ligand of 36-membered octaaminotetraphenol with copper(II) triflate gave a tetranuclear complex with a large Cu-O(phenoxo)-Cu angle (130.8(1)°) and small Cu-O(phenoxo)-Cu (91.5(1)°) and Cu-O(hydroxo)-Cu angles (93.1(1)°). The magnetic behavior was interpreted based on the structural data.

Original language	English
Pages (from-to)	316-317
Number of pages	2
Journal	Chemistry Letters
Issue number	4
DOIs	https://doi.org/10.1246/cl.2001.316
State	Published - 2001

ASJC Scopus subject areas

General Chemistry

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@article{0cdf8c3a488a40379eae49d638a7d124,

title = "Structure and magnetic property of a macrocyclic tetranuclear copper(II) complex with phenoxo-and hydroxo-bridges and large and small Cu-O-Cu angles",

abstract = "Reaction of a macrocyclic ligand of 36-membered octaaminotetraphenol with copper(II) triflate gave a tetranuclear complex with a large Cu-O(phenoxo)-Cu angle (130.8(1)°) and small Cu-O(phenoxo)-Cu (91.5(1)°) and Cu-O(hydroxo)-Cu angles (93.1(1)°). The magnetic behavior was interpreted based on the structural data.",

author = "Makoto Handa and Toshikazu Takemoto and Thompson, {Laurence K.} and Masahiro Mikuriya and Nobuyuki Nagao and Shinichiro Ikemi and Lim, {Jong Wan} and Tamotsu Sugimori and Ichiro Hiromitsu and Kuninobu Kasuga",

year = "2001",

doi = "10.1246/cl.2001.316",

language = "英語",

pages = "316--317",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "4",

}

TY - JOUR

T1 - Structure and magnetic property of a macrocyclic tetranuclear copper(II) complex with phenoxo-and hydroxo-bridges and large and small Cu-O-Cu angles

AU - Handa, Makoto

AU - Takemoto, Toshikazu

AU - Thompson, Laurence K.

AU - Mikuriya, Masahiro

AU - Nagao, Nobuyuki

AU - Ikemi, Shinichiro

AU - Lim, Jong Wan

AU - Sugimori, Tamotsu

AU - Hiromitsu, Ichiro

AU - Kasuga, Kuninobu

PY - 2001

Y1 - 2001

N2 - Reaction of a macrocyclic ligand of 36-membered octaaminotetraphenol with copper(II) triflate gave a tetranuclear complex with a large Cu-O(phenoxo)-Cu angle (130.8(1)°) and small Cu-O(phenoxo)-Cu (91.5(1)°) and Cu-O(hydroxo)-Cu angles (93.1(1)°). The magnetic behavior was interpreted based on the structural data.

AB - Reaction of a macrocyclic ligand of 36-membered octaaminotetraphenol with copper(II) triflate gave a tetranuclear complex with a large Cu-O(phenoxo)-Cu angle (130.8(1)°) and small Cu-O(phenoxo)-Cu (91.5(1)°) and Cu-O(hydroxo)-Cu angles (93.1(1)°). The magnetic behavior was interpreted based on the structural data.

UR - http://www.scopus.com/inward/record.url?scp=0035625788&partnerID=8YFLogxK

U2 - 10.1246/cl.2001.316

DO - 10.1246/cl.2001.316

M3 - 学術論文

AN - SCOPUS:0035625788

SN - 0366-7022

SP - 316

EP - 317

JO - Chemistry Letters

JF - Chemistry Letters

IS - 4

ER -

Structure and magnetic property of a macrocyclic tetranuclear copper(II) complex with phenoxo-and hydroxo-bridges and large and small Cu-O-Cu angles

Abstract

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