Stereoselective synthesis of cyclopentanones using dirhodium(II)-catalyzed intramolecular C-H insertion reaction

Keyphrases

• Stereoselective Synthesis 100%
• Dirhodium Complex 100%
• Cyclopentanone 100%
• Intramolecular C-H Insertion 100%
• C-H Insertion Reaction 100%
• Stereoselectivity 66%
• Optically Active 33%
• Silica Gel Column Chromatography 33%
• Alkyl 33%
• Diastereoisomers 33%
• Toluene 33%
• Diols 33%
• Tert 33%
• Diazo 33%
• Percentage Yield 33%
• Octane 33%
• Chemoselective 33%
• C-H Insertion 33%
• Oxonium Ylide 33%
• Keto Group 33%
• Ketoesters 33%
• Ester Group 33%
• LiAlH4 33%
• Acetonide 33%
• Dirhodium(II) Tetraacetate 33%
• Diazoketones 33%
• 1,2-shift 33%
• Benzenesulfonyl 33%
• Direct Reduction 33%
• Corey Lactone 33%

Chemistry

• Stereoselective Synthesis 100%
• Insertion Reaction 100%
• Cyclopentanone 100%
• Chemoselectivity 33%
• Lithium 33%
• Diol 33%
• Lactone 33%
• Octane 33%
• Column Chromatography 33%
• Oxonium Ylide 33%
• Ketoester 33%
• Stereoselectivity 33%
• Aluminum Hydride 33%
• formation 33%