Stereoselective cyclization using palladium(II) catalyst via hemiacetal intermediates

Masahiro Miyazawa; Yukari Hirose; Magsarjav Narantsetseg; Hajime Yokoyama; Seiji Yamaguchi; Yoshiro Hirai

doi:10.1016/j.tetlet.2004.02.058

Stereoselective cyclization using palladium(II) catalyst via hemiacetal intermediates

Masahiro Miyazawa, Yukari Hirose, Magsarjav Narantsetseg, Hajime Yokoyama, Seiji Yamaguchi, Yoshiro Hirai^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

A stereoselective palladium-catalyzed cyclization of 3-phenyl-7-hydroxy-5- heptenal was developed. The reaction was carried out to give 2,4,6-trisubstituted tetrahydropyran with highly controlled 4,6-cis stereochemistry.

Original language	English
Pages (from-to)	2883-2886
Number of pages	4
Journal	Tetrahedron Letters
Volume	45
Issue number	14
DOIs	https://doi.org/10.1016/j.tetlet.2004.02.058
State	Published - 2004/03/29

Keywords

Cyclization
Hemiacetal
Palladium catalyst
Tetrahydropyran

ASJC Scopus subject areas

Organic Chemistry
Drug Discovery
Biochemistry

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10.1016/j.tetlet.2004.02.058

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title = "Stereoselective cyclization using palladium(II) catalyst via hemiacetal intermediates",

abstract = "A stereoselective palladium-catalyzed cyclization of 3-phenyl-7-hydroxy-5- heptenal was developed. The reaction was carried out to give 2,4,6-trisubstituted tetrahydropyran with highly controlled 4,6-cis stereochemistry.",

keywords = "Cyclization, Hemiacetal, Palladium catalyst, Tetrahydropyran",

author = "Masahiro Miyazawa and Yukari Hirose and Magsarjav Narantsetseg and Hajime Yokoyama and Seiji Yamaguchi and Yoshiro Hirai",

note = "Funding Information: This research was financially supported by a Grant-in-Aid from the Ministry of Education, Science, Sports and Culture, Japan.",

year = "2004",

month = mar,

day = "29",

doi = "10.1016/j.tetlet.2004.02.058",

language = "英語",

volume = "45",

pages = "2883--2886",

journal = "Tetrahedron Letters",

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publisher = "Elsevier Ltd.",

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TY - JOUR

T1 - Stereoselective cyclization using palladium(II) catalyst via hemiacetal intermediates

AU - Miyazawa, Masahiro

AU - Hirose, Yukari

AU - Narantsetseg, Magsarjav

AU - Yokoyama, Hajime

AU - Yamaguchi, Seiji

AU - Hirai, Yoshiro

N1 - Funding Information: This research was financially supported by a Grant-in-Aid from the Ministry of Education, Science, Sports and Culture, Japan.

PY - 2004/3/29

Y1 - 2004/3/29

N2 - A stereoselective palladium-catalyzed cyclization of 3-phenyl-7-hydroxy-5- heptenal was developed. The reaction was carried out to give 2,4,6-trisubstituted tetrahydropyran with highly controlled 4,6-cis stereochemistry.

AB - A stereoselective palladium-catalyzed cyclization of 3-phenyl-7-hydroxy-5- heptenal was developed. The reaction was carried out to give 2,4,6-trisubstituted tetrahydropyran with highly controlled 4,6-cis stereochemistry.

KW - Cyclization

KW - Hemiacetal

KW - Palladium catalyst

KW - Tetrahydropyran

UR - http://www.scopus.com/inward/record.url?scp=1642328126&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2004.02.058

DO - 10.1016/j.tetlet.2004.02.058

M3 - 学術論文

AN - SCOPUS:1642328126

SN - 0040-4039

VL - 45

SP - 2883

EP - 2886

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 14

ER -

Stereoselective cyclization using palladium(II) catalyst via hemiacetal intermediates

Abstract

Keywords

ASJC Scopus subject areas

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