Stepwise synthesis and characterization of germa[4], [5], [8], and [10]pericyclynes

Hiroki Tanimoto; Tomohiko Nagao; Taro Fujiwara; Yasuhiro Nishiyama; Tsumoru Morimoto; Toshimasa Suzuka; Ken Tsutsumi; Kiyomi Kakiuchi

doi:10.1039/c5dt01411e

Stepwise synthesis and characterization of germa[4], [5], [8], and [10]pericyclynes

Hiroki Tanimoto^*, Tomohiko Nagao, Taro Fujiwara, Yasuhiro Nishiyama, Tsumoru Morimoto, Toshimasa Suzuka, Ken Tsutsumi, Kiyomi Kakiuchi

^*Corresponding author for this work

Biorecognition Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The stepwise syntheses of germa[N]pericyclynes, including [5]pericyclynes, and their characterization are described. The yields of germa[4] and [8]pericyclynes were improved significantly compared to those obtained in previous studies. The routes reported herein afforded the novel germa[5] and [10]pericyclynes, which were characterized by X-ray crystallography, UV-Vis spectroscopy, and fluorescence emission spectroscopy. A unique fluorescence emission was observed for the large germa[10]pericyclyne ring.

Original language	English
Pages (from-to)	11811-11818
Number of pages	8
Journal	Dalton Transactions
Volume	44
Issue number	26
DOIs	https://doi.org/10.1039/c5dt01411e
State	Published - 2015/07/14

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Inorganic Chemistry

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title = "Stepwise synthesis and characterization of germa[4], [5], [8], and [10]pericyclynes",

abstract = "The stepwise syntheses of germa[N]pericyclynes, including [5]pericyclynes, and their characterization are described. The yields of germa[4] and [8]pericyclynes were improved significantly compared to those obtained in previous studies. The routes reported herein afforded the novel germa[5] and [10]pericyclynes, which were characterized by X-ray crystallography, UV-Vis spectroscopy, and fluorescence emission spectroscopy. A unique fluorescence emission was observed for the large germa[10]pericyclyne ring.",

author = "Hiroki Tanimoto and Tomohiko Nagao and Taro Fujiwara and Yasuhiro Nishiyama and Tsumoru Morimoto and Toshimasa Suzuka and Ken Tsutsumi and Kiyomi Kakiuchi",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

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doi = "10.1039/c5dt01411e",

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TY - JOUR

T1 - Stepwise synthesis and characterization of germa[4], [5], [8], and [10]pericyclynes

AU - Tanimoto, Hiroki

AU - Nagao, Tomohiko

AU - Fujiwara, Taro

AU - Nishiyama, Yasuhiro

AU - Morimoto, Tsumoru

AU - Suzuka, Toshimasa

AU - Tsutsumi, Ken

AU - Kakiuchi, Kiyomi

PY - 2015/7/14

Y1 - 2015/7/14

N2 - The stepwise syntheses of germa[N]pericyclynes, including [5]pericyclynes, and their characterization are described. The yields of germa[4] and [8]pericyclynes were improved significantly compared to those obtained in previous studies. The routes reported herein afforded the novel germa[5] and [10]pericyclynes, which were characterized by X-ray crystallography, UV-Vis spectroscopy, and fluorescence emission spectroscopy. A unique fluorescence emission was observed for the large germa[10]pericyclyne ring.

AB - The stepwise syntheses of germa[N]pericyclynes, including [5]pericyclynes, and their characterization are described. The yields of germa[4] and [8]pericyclynes were improved significantly compared to those obtained in previous studies. The routes reported herein afforded the novel germa[5] and [10]pericyclynes, which were characterized by X-ray crystallography, UV-Vis spectroscopy, and fluorescence emission spectroscopy. A unique fluorescence emission was observed for the large germa[10]pericyclyne ring.

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U2 - 10.1039/c5dt01411e

DO - 10.1039/c5dt01411e

M3 - 学術論文

AN - SCOPUS:84934924372

SN - 1477-9226

VL - 44

SP - 11811

EP - 11818

JO - Dalton Transactions

JF - Dalton Transactions

IS - 26

ER -

Stepwise synthesis and characterization of germa[4], [5], [8], and [10]pericyclynes

Abstract

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