Solubilization of meso-carbon materials by butylation with dibutylzinc and butyl iodide

Yan Zhang; Koh Kidena; Satoru Murata; Masakatsu Nomura; Yoshiharu Yoneyama; Tsutomu Kato

doi:10.1246/cl.1996.491

Solubilization of meso-carbon materials by butylation with dibutylzinc and butyl iodide

Yan Zhang, Koh Kidena, Satoru Murata, Masakatsu Nomura^*, Yoshiharu Yoneyama, Tsutomu Kato

^*Corresponding author for this work

Department of Art and Design

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Abstract

Solubilization of meso-carbon microbeads (MCMB) with dibutylzinc-butyl iodide reagents was investigated, this reaction giving tetrahydrofuran-soluble materials in 94-97% yield. This is the first example, to our knowledge, for effective solubilization of these meso-carbon materials. The Mode of introduction of butyl groups was also clarified by using ¹³C-NMR of butylated samples.

Original language	English
Pages (from-to)	491-492
Number of pages	2
Journal	Chemistry Letters
Issue number	6
DOIs	https://doi.org/10.1246/cl.1996.491
State	Published - 1996

ASJC Scopus subject areas

General Chemistry

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10.1246/cl.1996.491

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title = "Solubilization of meso-carbon materials by butylation with dibutylzinc and butyl iodide",

abstract = "Solubilization of meso-carbon microbeads (MCMB) with dibutylzinc-butyl iodide reagents was investigated, this reaction giving tetrahydrofuran-soluble materials in 94-97% yield. This is the first example, to our knowledge, for effective solubilization of these meso-carbon materials. The Mode of introduction of butyl groups was also clarified by using 13C-NMR of butylated samples.",

author = "Yan Zhang and Koh Kidena and Satoru Murata and Masakatsu Nomura and Yoshiharu Yoneyama and Tsutomu Kato",

year = "1996",

doi = "10.1246/cl.1996.491",

language = "英語",

pages = "491--492",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "6",

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T1 - Solubilization of meso-carbon materials by butylation with dibutylzinc and butyl iodide

AU - Zhang, Yan

AU - Kidena, Koh

AU - Murata, Satoru

AU - Nomura, Masakatsu

AU - Yoneyama, Yoshiharu

AU - Kato, Tsutomu

PY - 1996

Y1 - 1996

N2 - Solubilization of meso-carbon microbeads (MCMB) with dibutylzinc-butyl iodide reagents was investigated, this reaction giving tetrahydrofuran-soluble materials in 94-97% yield. This is the first example, to our knowledge, for effective solubilization of these meso-carbon materials. The Mode of introduction of butyl groups was also clarified by using 13C-NMR of butylated samples.

AB - Solubilization of meso-carbon microbeads (MCMB) with dibutylzinc-butyl iodide reagents was investigated, this reaction giving tetrahydrofuran-soluble materials in 94-97% yield. This is the first example, to our knowledge, for effective solubilization of these meso-carbon materials. The Mode of introduction of butyl groups was also clarified by using 13C-NMR of butylated samples.

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U2 - 10.1246/cl.1996.491

DO - 10.1246/cl.1996.491

M3 - 学術論文

AN - SCOPUS:0030488564

SN - 0366-7022

SP - 491

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

Solubilization of meso-carbon materials by butylation with dibutylzinc and butyl iodide

Abstract

ASJC Scopus subject areas

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