TY - JOUR
T1 - Revisitation of cycloheptatriene derivatives as a building block for various substituted and fused 1,6-methano[10]annulenes and substituted 4,9-methanothia[11]annulenes
AU - Kuroda, Shigeyasu
AU - Kajioka, Takanori
AU - Fukuta, Atsushi
AU - Thanh, Nguyen Chung
AU - Zhang, Yanmei
AU - Miyatake, Ryuta
AU - Mouri, Masaru
AU - Zuo, Shengli
AU - Oda, Mitsunori
PY - 2007/2
Y1 - 2007/2
N2 - A synthetic maneuver from 1,6-diacetyl- and 1,6-diformyl-1,3,5-cycloheptatrienes toward various 1,6-methano[10]annulenes, such as diaryl-substituted, cyclobutene-annulated, and thiophene-annulated derivatives and its quinodimethane-type compound, and 4,9-methanothia[11]annulenes is spotlighted based on our recent research efforts. The crystal structure analysis of the annulenes, discussion of mechanistic details of a key cyclization step and application of some annulene derivatives to a material in organic electroluminescent devices are also described.
AB - A synthetic maneuver from 1,6-diacetyl- and 1,6-diformyl-1,3,5-cycloheptatrienes toward various 1,6-methano[10]annulenes, such as diaryl-substituted, cyclobutene-annulated, and thiophene-annulated derivatives and its quinodimethane-type compound, and 4,9-methanothia[11]annulenes is spotlighted based on our recent research efforts. The crystal structure analysis of the annulenes, discussion of mechanistic details of a key cyclization step and application of some annulene derivatives to a material in organic electroluminescent devices are also described.
KW - Cyclobutenes
KW - Molecular orbital calculations
KW - Organic electroluminescent device
KW - Quinodimethanes
KW - Thiophenes
KW - X-ray crystallographic analysis
UR - http://www.scopus.com/inward/record.url?scp=33846994792&partnerID=8YFLogxK
U2 - 10.2174/157019307779815866
DO - 10.2174/157019307779815866
M3 - 学術論文
AN - SCOPUS:33846994792
SN - 1570-193X
VL - 4
SP - 31
EP - 49
JO - Mini-Reviews in Organic Chemistry
JF - Mini-Reviews in Organic Chemistry
IS - 1
ER -