Reversible conversion of tetranuclear, trinuclear, and mononuclear palladium(II) complexes with d-penicillaminate

Nobuto Yoshinari; Yusuke Hirai; Tatsuya Kawamoto; Asako Igashira-Kamiyama; Kiyoshi Tsuge; Takumi Konno

doi:10.1246/cl.2009.1056

Reversible conversion of tetranuclear, trinuclear, and mononuclear palladium(II) complexes with d-penicillaminate

Nobuto Yoshinari^*, Yusuke Hirai, Tatsuya Kawamoto, Asako Igashira-Kamiyama, Kiyoshi Tsuge, Takumi Konno

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The 1:1 reaction of [PdCl₄]^2- with D-penicillamine (DH₂pen) gave a S-bridged tetranuclear complex, [Pd ₄Cl₄(DHpen)₄] ([1]). Complex [1] was converted to a S-bridged trinuclear complex, [Pd₃(D-pen)₃] ([2]), which was further converted to a mononuclear complex, K2[Pd(D-pen)2] (K ₂[3]). The reverse conversion of [2] to [1] was also achieved.

Original language	English
Pages (from-to)	1056-1057
Number of pages	2
Journal	Chemistry Letters
Volume	38
Issue number	11
DOIs	https://doi.org/10.1246/cl.2009.1056
State	Published - 2009

ASJC Scopus subject areas

General Chemistry

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@article{92f6d9c41ea3404c9013396d26236513,

title = "Reversible conversion of tetranuclear, trinuclear, and mononuclear palladium(II) complexes with d-penicillaminate",

abstract = "The 1:1 reaction of [PdCl4]2- with D-penicillamine (DH2pen) gave a S-bridged tetranuclear complex, [Pd 4Cl4(DHpen)4] ([1]). Complex [1] was converted to a S-bridged trinuclear complex, [Pd3(D-pen)3] ([2]), which was further converted to a mononuclear complex, K2[Pd(D-pen)2] (K 2[3]). The reverse conversion of [2] to [1] was also achieved.",

author = "Nobuto Yoshinari and Yusuke Hirai and Tatsuya Kawamoto and Asako Igashira-Kamiyama and Kiyoshi Tsuge and Takumi Konno",

year = "2009",

doi = "10.1246/cl.2009.1056",

language = "英語",

volume = "38",

pages = "1056--1057",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "11",

}

TY - JOUR

T1 - Reversible conversion of tetranuclear, trinuclear, and mononuclear palladium(II) complexes with d-penicillaminate

AU - Yoshinari, Nobuto

AU - Hirai, Yusuke

AU - Kawamoto, Tatsuya

AU - Igashira-Kamiyama, Asako

AU - Tsuge, Kiyoshi

AU - Konno, Takumi

PY - 2009

Y1 - 2009

N2 - The 1:1 reaction of [PdCl4]2- with D-penicillamine (DH2pen) gave a S-bridged tetranuclear complex, [Pd 4Cl4(DHpen)4] ([1]). Complex [1] was converted to a S-bridged trinuclear complex, [Pd3(D-pen)3] ([2]), which was further converted to a mononuclear complex, K2[Pd(D-pen)2] (K 2[3]). The reverse conversion of [2] to [1] was also achieved.

AB - The 1:1 reaction of [PdCl4]2- with D-penicillamine (DH2pen) gave a S-bridged tetranuclear complex, [Pd 4Cl4(DHpen)4] ([1]). Complex [1] was converted to a S-bridged trinuclear complex, [Pd3(D-pen)3] ([2]), which was further converted to a mononuclear complex, K2[Pd(D-pen)2] (K 2[3]). The reverse conversion of [2] to [1] was also achieved.

UR - http://www.scopus.com/inward/record.url?scp=75249095644&partnerID=8YFLogxK

U2 - 10.1246/cl.2009.1056

DO - 10.1246/cl.2009.1056

M3 - 学術論文

AN - SCOPUS:75249095644

SN - 0366-7022

VL - 38

SP - 1056

EP - 1057

JO - Chemistry Letters

JF - Chemistry Letters

IS - 11

ER -

Reversible conversion of tetranuclear, trinuclear, and mononuclear palladium(II) complexes with d-penicillaminate

Abstract

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