Relay catalysis using a gold(i) complex/Brønsted acid binary system for the synthesis of bezoxasiloles

Yoshikazu Horino; Yu Takahashi; Yuichi Nakashima; Hitoshi Abe

doi:10.1039/c3ra47149g

Relay catalysis using a gold(i) complex/Brønsted acid binary system for the synthesis of bezoxasiloles

Yoshikazu Horino^*, Yu Takahashi, Yuichi Nakashima, Hitoshi Abe

^*Corresponding author for this work

Applied Chemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A strategy for the synthesis of synthetically useful benzoxasilole derivatives by combining a gold(i) complex/Brønsted acid binary system and a temporary silicon tether method has been developed that involves relay catalytic cascade intramolecular allylation of alkynes by a gold(i) complex and addition of silanols to enones by a Brønsted acid.

Original language	English
Pages (from-to)	6215-6218
Number of pages	4
Journal	RSC Advances
Volume	4
Issue number	12
DOIs	https://doi.org/10.1039/c3ra47149g
State	Published - 2014

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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10.1039/c3ra47149g

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title = "Relay catalysis using a gold(i) complex/Br{\o}nsted acid binary system for the synthesis of bezoxasiloles",

abstract = "A strategy for the synthesis of synthetically useful benzoxasilole derivatives by combining a gold(i) complex/Br{\o}nsted acid binary system and a temporary silicon tether method has been developed that involves relay catalytic cascade intramolecular allylation of alkynes by a gold(i) complex and addition of silanols to enones by a Br{\o}nsted acid.",

author = "Yoshikazu Horino and Yu Takahashi and Yuichi Nakashima and Hitoshi Abe",

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doi = "10.1039/c3ra47149g",

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AU - Horino, Yoshikazu

AU - Takahashi, Yu

AU - Nakashima, Yuichi

AU - Abe, Hitoshi

PY - 2014

Y1 - 2014

N2 - A strategy for the synthesis of synthetically useful benzoxasilole derivatives by combining a gold(i) complex/Brønsted acid binary system and a temporary silicon tether method has been developed that involves relay catalytic cascade intramolecular allylation of alkynes by a gold(i) complex and addition of silanols to enones by a Brønsted acid.

AB - A strategy for the synthesis of synthetically useful benzoxasilole derivatives by combining a gold(i) complex/Brønsted acid binary system and a temporary silicon tether method has been developed that involves relay catalytic cascade intramolecular allylation of alkynes by a gold(i) complex and addition of silanols to enones by a Brønsted acid.

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U2 - 10.1039/c3ra47149g

DO - 10.1039/c3ra47149g

M3 - 学術論文

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SN - 2046-2069

VL - 4

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JO - RSC Advances

JF - RSC Advances

IS - 12

ER -

Relay catalysis using a gold(i) complex/Brønsted acid binary system for the synthesis of bezoxasiloles

Abstract

ASJC Scopus subject areas

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